54480-52-3Relevant academic research and scientific papers
Stereospecific aerobic oxidative dehydrocoupling of P(O)H bonds with amines catalyzed by copper
Zhou, Yongbo,Yang, Jia,Chen, Tieqiao,Yin, Shuang-Feng,Han, Daoqing,Han, Li-Biao
supporting information, p. 400 - 402 (2014/04/17)
Copper-catalyzed stereospecific oxidative dehydrocouplings of P(O)H bonds with amines under air took place effi-ciently at room temperature to afford the corresponding amidophosphorus compounds in high yields. Mechanistic studies showed that this dehydroc
Trichlorocyanuric acid: An efficient reagent for one-pot synthesis of Ptychodiscus brevis (PB-1) toxin and its derivatives
Gupta, Arvind K.,Acharya, Jyotiranjan,Dubey, Devendra K.,Kaushik, Mahabir P.
, p. 29 - 33 (2008/02/02)
Trichlorocyanuric acid is an efficient regent for simple and one-pot synthesis of dialkyl, N-cycloctylphosphoraamidates (PB-1) and its various derivatives in excellent yields. The procedure is operationally simple and involves the reaction of various dialkylphosphites with trichloroisocyanuric acid in acetonitrile and subsequent treatment with amines in presence KF-celite to give PB-1 and derivatives.
THE APPLICATION OF DIALKYLPHOSPHITE AS THE AMINO PROTECTION REAGENT IN ORGANIC SYNTHESIS
Zhao, Yu-Fen,Ji, Gai-Jiao,Xi, She-Kang,Tang, Hue-Gong,Song, Ai-Teng,Wei, Shou-Zuo
, p. 155 - 158 (2007/10/02)
The acid hydrolysis of N-phenyl-N-dialkyl-phosphoramidates was studied by HPLC, the N-phenyl-N-diisopropylphosphoramidate has half life 53 min in 6N HCl at 50 deg C.The P-N bonds of these phosphoryl derivatives also show a relative stability in organic and Lewis acids.
REACTION OF SULFENAMIDES WITH DI-ALKYL AND TRIALKYL PHOSPHITES. AN EFFICIENT SYNTHESIS OF PHOSPHORAMIDATES BY UNUSUAL SUBSTITUTION AT S-N BOND IN (2-BENZOTHIAZOLYL)SULFENAMIDES
Torii, Sigeru,Sayo, Noboru,Tanaka, Hideo
, p. 695 - 698 (2007/10/02)
Regioselective attack of the trivalent phosphorus atom of dialkyl and trialkyl phosphites on either nitrogen or sulfur atom of sulfenamides has been found.The reaction of phenylsulfenamides with dialkyl phosphites yielded phosphorothiolates, whereas the treatment of (2-benzothiazolyl)sulfenamides with dialkyl and trialkyl phosphites gave phosphoramidates in excellent yields.
