545437-24-9

Basic information

• Product Name: N-(diphenylmethyl)cyclopropylcarboxamide
• Synonyms: N-(diphenylmethyl)cyclopropylcarboxamide
• CAS NO: 545437-24-9
• Molecular Weight: 251.328
• Mol File: 545437-24-9.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: N-(diphenylmethyl)cyclopropylcarboxamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-(diphenylmethyl)cyclopropylcarboxamide(545437-24-9)
• EPA Substance Registry System: N-(diphenylmethyl)cyclopropylcarboxamide(545437-24-9)

Safety Data

• Hazardous Substances Data: 545437-24-9(Hazardous Substances Data)

Upstream product

• 101-81-5 Diphenylmethane 
• 5500-21-0 cyclopropropanecarbonitrile 
• 4023-34-1 cyclopropanecarboxylic acid chloride 
• 91-00-9 Benzhydrylamine 
• 91-01-0 1,1-Diphenylmethanol 

Relevant articles and documents

Method for synthesizing amide compound by taking nitrile and diaryl methane as raw materials

The invention discloses a method for synthesizing an amide compound by taking nitrile and diaryl methane as raw materials, the method comprises the following steps: taking diaryl methane as a reaction raw material, nitrile as a raw material and a solvent, 2, 3-dichloro-5, 6-dinitrile group-1, 4-benzoquinone (DDQ) and tert-butyl nitrite (TBN) as catalysts, acid as an auxiliary agent and oxygen as an oxidizing agent, reacting under the conditions of normal temperature, normal pressure and blue light irradiation, and after the reaction is finished, carrying out separation treatment to obtain the amide compound. According to the method, the problem of metal residues in the product can be solved, oxygen is used as a terminal oxidizing agent, the method is environmentally friendly, and energy can be saved.

Manganese(III) acetate catalyzed oxidative amination of benzylic C(sp3)-H bonds with nitriles

Mn-Catalyzed oxidative amination of benzylic C(sp3)-H bonds with nitriles is disclosed, which enables the synthesis of a broad range of secondary amides in moderate to excellent yields under mild conditions. The interaction between Mn(iii) and DDQ facilitates the oxidation and makes it highly efficient and selective.

Preparation of different amides via Ritter reaction from alcohols and nitriles in the presence of silica-bonded N-propyl sulphamic acid (SBNPSA) under solvent-free conditions

A number of methods have been proposed for the modification of the Ritter reaction. However, many of these methods involve the use of strongly acidic conditions, stoichiometric amounts of reagents, harsh reaction conditions and extended reaction times. Th