54550-26-4Relevant articles and documents
Oxidative C-H Acyloxylation of Acetone with Carboxylic Acids under Iodine Catalysis
Zhou, Xiao-Yu,Chen, Xia
supporting information, p. 1654 - 1662 (2021/01/21)
Iodine-catalyzed oxidative C(sp 3)-H acyloxylation of acetone with carboxylic acids has been developed. The method employs iodide as catalyst and sodium chlorite as oxidant. Substituted benzoic acids, naphthoic acids and heteroaromatic carboxyl
Facile oxidative hydrolysis of acetals to esters using hypervalent iodine(III)/LiBr combination in water
Panchan, Waraporn,Chiampanichayakul, Supanimit,Snyder, Deanna L.,Yodbuntung, Siriporn,Pohmakotr, Manat,Reutrakul, Vichai,Jaipetch, Thaworn,Kuhakarn, Chutima
scheme or table, p. 2732 - 2735 (2010/05/17)
The combination of (diacetoxy)iodobenzene (PhI(OAc)2, DIB) and lithium bromide (LiBr) efficiently oxidized cyclic and acyclic acetals to the corresponding hydroxyalkyl carboxylic esters and simple esters in good to excellent yields. The merits of this reaction are that it employs commercially available and non-explosive hypervalent iodine(III) reagent, water as the solvent, a short reaction time, and mild reaction conditions.
Synthesis of 2-Substituted 1H-Benzoxazepin-5-ones
Sicker, Dieter
, p. 336 - 344 (2007/10/02)
An approach to the hitherto unknown class of 1H-benz>e>oxazepin-5-ones is given based on reduction and cyclization of appropriate acyclic ortho-nitro compounds as starting material.Thus, some 2-substituted derivatives (3a-i) were synthesized by catal