5460-52-6Relevant academic research and scientific papers
METAL-FREE DIRECT ARYLATION OF DIALKYL PHOSPHONATES FOR THE SYNTHESIS OF MIXED ALKYL ARYL PHOSPHONATES
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Paragraph 00385; 00402; 00442, (2019/02/15)
Provided herein are phosphates, thiophosphates, phosphonates, and phosphinates, methods of making same, and methods of using these compounds and methods for the generation of pharmaceutically relevant phosphate, phosphonate, and phosphinate analogs. This
Tf2O-Promoted Activating Strategy of Phosphate Analogues: Synthesis of Mixed Phosphates and Phosphinate
Huang, Hai,Ash, Jeffrey,Kang, Jun Yong
supporting information, p. 4938 - 4941 (2018/08/24)
A metal-, toxic chloride reagent-free activating strategy of various phosphates has been developed. This method enables the facile synthesis of functional phosphates such as alkyl phosphates, aza phosphates, thiophosphate, and mixed diaryl phosphates. A transient phosphorylpyridin-1-ium species in situ generated from phosphates with Tf2O/pyridine readily undergoes a substitution reaction with diverse nucleophiles to form versatile phosphate compounds.
Photoinduced three-component reaction: A convenient access to 3-arylacetals or 3-arylketals
Lazzaroni, Simone,Protti, Stefano,Fagnoni, Maurizio,Albini, Angelo
supporting information; experimental part, p. 349 - 352 (2009/08/15)
(Chemical Equation Presented) A mild and versatile method for the photoinduced three-component synthesis of 3-arylacetals and ketals is presented. Desired targets are smoothly obtained by irradiating aromatic halides or esters in alcohols, in the presence
