54620-84-7Relevant academic research and scientific papers
The Stereochemistry of Organometallic Compounds. XXXV. Hydroformylation of ortho-Propenylanilines and ortho-Propenylphenols: a New Route to 4,5-Dihydro-3H-1-benzazepines
Anastasiou, Despina,Jackson, W. Roy
, p. 21 - 37 (2007/10/02)
Rhodium-catalyzed hydroformylation of readily available ortho-propenylanilines gives 4,5-dihydro-3H-1-benzazepines together with small amounts of substituted 3-methylquinolines (15percent).The regioselectivity of these reactions and the hydroformylation of related ortho-propenylphenols are discussed.
A New Metal-catalysed Route to 4,5-Dihydro-3H-1-Benzazepines
Anastasiou, Despina,Jackson, W. Roy
, p. 1205 - 1206 (2007/10/02)
A new, short, high-yielding route to 4,5-dihydro-3H-1-benzazepines has been developed based on the rhodium-catalysed hydroformylation of readily available ortho-propenylbenzeneamines; a comparison with the hydroformylation of the corresponding ortho-propenylphenols is made.
