54636-61-2

Usage

Explanation

The compound consists of 10 carbon atoms, 11 hydrogen atoms, and 1 bromine atom.

Explanation

The compound is a derivative of benzene with a bromine atom and a propenyl group attached to the benzene ring. The propenyl group has three carbon atoms with a double bond between the first and second carbon atoms.

Explanation

This name highlights the presence of a bromine atom and a propenyl group attached to a toluene molecule.

Explanation

The compound contains a bromine atom, a propenyl group (with a double bond), and a methyl group attached to the benzene ring.

Explanation

The compound is utilized in the synthesis of various organic compounds and serves as a precursor for the production of other chemicals.

Explanation

Due to its potential hazards, it is essential to follow proper safety protocols when working with 1-(3-bromo-1-propen-1-yl)-2-methylbenzene.

Explanation

The appearance of the compound (e.g., color, state of matter) is not mentioned in the given information.

Explanation

The solubility of the compound in various solvents is not provided in the material.

Explanation

The boiling point of the compound is not mentioned in the given information.

Explanation

The melting point of the compound is not provided in the material.

Structure

1-(3-bromo-1-propen-1-yl)-2-methylbenzene

Functional groups

Bromine atom, propenyl group, and methyl group

Use

Organic synthesis and intermediate in the production of other chemicals

Hazardous nature

Handle with caution

Upstream product

• 39627-62-8 1-(o-tolyl)-2-propen-1-ol 
• 20850-01-5 3-(2-methylphenyl)-2-propen-1-ol 
• 529-20-4 2-methylphenyl aldehyde 
• 24393-48-4 2-methyl-cinnamic acid ethyl ester 

Downstream Products

• 1182847-28-4 (S)-1′-methyl-2′-(pent-1-en-3-yl)benzene 
• 1202576-43-9 (+)-(S)-1-(1-(4-fluorophenyl)allyl)-2-methylbenzene 
• 1202576-47-3 (+)-(S)-1-methyl-2-(1-(4-methylphenyl)allyl)benzene 
• 1202576-38-2 (-)-(S)-1-methyl-2-(1-phenylallyl)benzene 
• 94576-03-1 2-dimethylamino-1-phenyl-3-(o-tolyl)pent-4-en-1-one 
• 4549-82-0 (E)-2-methylcinnamaldehyde 

Relevant academic research and scientific papers

Arene Trifunctionalization with Highly Fused Ring Systems through a Domino Aryne Nucleophilic and Diels–Alder Cascade

A convenient and efficient domino aryne process was developed under transition-metal-free conditions to generate a range of tetra- and pentacyclic ring systems. This transformation was realized via a 1,2-benzdiyne through a nucleophilic and Diels–Alder reaction cascade using styrene as the diene moiety. Three new chemical bonds, namely one C?N and two C?C bonds, and two benzofused rings could be constructed concomitantly, which was made possible by distinct chemoselective control at both the 1,2-aryne and 2,3-aryne stages. Moreover, in-depth studies were carried out on the domino aryne precursors and controlling the diastereoselectivity.

Olefin Oxyamination with Unfunctionalized N-Alkylanilines

N-Alkylanilines have rarely been used in oxyamination reactions, due to the normally necessary pre-functionalization of the N-atom. Also, the formation of aminium radical cations (ARCs) of anilines bearing alkyl substituents is plagued by the ARC's tendency to instantaneously convert to α-amino radicals or iminium ions. We present a readily available reagent combination that addresses both challenges, and thus allows for an oxyamination with N-alkylanilines via ARCs as the crucial reactive intermediates and excellent diastereoselectivity. (Figure presented.).

Copper-catalyzed nucleophilic trifluoromethylation of allylic halides: A simple approach to allylic trifluoromethylation

Trifluoromethylation: The treatment of allylic halides with trifluoromethyltrimethylsilane in the presence of a catalytic amount of copper(I) thiophene-2-carboxylate (CuTC) gives the corresponding allylic trifluoromethylation products in good to high yields and with complete regioselectivity (see scheme). The use of THF as a solvent is crucial for obtaining good yields of product.