54662-02-1Relevant articles and documents
Palladium-Catalyzed Oxidative C–H Alkoxycarbonylation of Arenes with Alkylcarbazates Directed by N-Heterocyclic Substituents
Yogesh Kumar, Gujjenahalli Ramalingaiah,Begum, Noor Shahina
supporting information, p. 4698 - 4704 (2020/07/04)
With alkyl carbazates as the green ester source, a novel palladium-catalyzed oxidative free radical carbonylative transformation of the C–H bond on aromatic rings to produce esters has been developed. Good yields of the corresponding products have been obtained with wide functional group tolerance and excellent regioselectivity. A variety of alkyl carbazates are found to be suitable reactants for the ortho-alkoxycarbonylation on the aromatic ring.
Synthesis of 6-carboxylated phenanthridines by oxidative alkoxycarbonylation-cyclization of 2-isocyanobiphenyls with carbazates
Wang, Gao,Chen, Shan-Yong,Yu, Xiao-Qi
supporting information, p. 5338 - 5341 (2015/01/09)
An iron-catalyzed synthesis of 6-carboxylated phenanthridines starting with readily prepared isocyanides and carbazates was developed. Reactions occurred via addition of alkoxycarbonyl radicals to the isocyanide group and subsequent intramolecular cyclization.
7-Oxabicycloheptane hydrazone prostaglandin analogs useful in treating thrombolytic diseases
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, (2008/06/13)
7-Oxabicycloheptane hydrazone prostaglandin analogs are provided having the structural formula STR1 and including all stereoisomers thereof. pa The compounds are cardiovascular agents useful, for example, in the treatment of thrombolytic disease.