54669-83-9

Upstream product

• 6651-36-1 1-(Trimethylsilyloxy)cyclohexene 
• 120312-66-5 C₁₅H₁₄IO⁽¹⁺⁾*BF₄^(1-) 
• 1125-99-1 1-(1-Cyclohexen-1-yl)pyrrolidine 
• 619-41-0 4-(bromoacetyl)toluene 
• 622-97-9 1-ethenyl-4-methylbenzene 
• 108-94-1 cyclohexanone 
• 1056477-06-5 2-bromocyclohexanone 
• 670-80-4 4-cyclohexen-1-ylmorpholine 
• 80676-77-3 1-(1-t-butyldimethylsiloxyethenyl)-4-methylbenzene 

Downstream Products

• 54670-35-8 2-hydroxy-5-(2-p-tolyl-4,5,6,7-tetrahydro-indol-1-yl)-benzoic acid 
• 120110-27-2 2-p-methylphenyl-4,5,6,7-tetrahydrothiophene 

Relevant academic research and scientific papers

Organic Dye-Catalyzed Intermolecular Radical Coupling of α-Bromocarbonyls with Olefins: Photocatalytic Synthesis of 1,4-Ketocarbonyls Using Air as an Oxidant

An organic dye-catalyzed visible light-promoted ketocarbonylation protocol of vinyl arenes has been disclosed with the help of α-bromocarbonyls where aerial oxygen played a role of an oxidant to install the keto-oxygen functionality. This unique process i

Sunlight-driven synthesis of γ-diketones via oxidative coupling of enamines with silyl enol ethers catalyzed by [Ru(bpy)3]2+

A photosensitizer [Ru(bpy)3]2+ catalyzes oxidative coupling reaction of enamines with silyl enol ethers under visible light irradiation by a Xe lamp or sunlight to produce γ-diketones. A 2e-oxidation process involved in this reaction

The cascade carbo-carbonylation of unactivated alkenes catalyzed by an organocatalyst and a transition metal catalyst: A facile approach to γ-diketones and γ-carbonyl aldehydes from arylalkenes under air

A novel cascade carbo-carbonylation reaction of unactivated arylalkenes with ketones or aldehydes was catalyzed by an organocatalyst and a transition metal catalyst via a SOMO-enamine under air, affording a simple approach to γ-diketones and γ-carbonyl aldehydes. The Royal Society of Chemistry 2010.

Carbon-Carbon Bond Formation in Reactions of PhIO*HBF4/Silyl Enol Ether Adduct with Alkenes or Silyl Enol Ethers

A new method for generation of reactive α-ketomethyl aryliodonium intermediates from silyl enol ethers and PhIO*HBF4 has been developed.Reactions of PhIO*HBF4/silyl enol ether adduct with alkenes (1-hexene, cyclohexene, α-methylstyrene, allyltrimethylsilane, 2,3-dimethyl-2-butene) yielded products of allylic alkylation or (in case of 2,3-dimethyl-2-butene) a substituted dihydrofuran.Reactions of adducts from PhIO/HBF4 and silyl enol ethers of acetophone, p-chloroacetophenone, p-methylacetophenone, and p-nitroacetophenone with various silyl enol ethers led to unsymmetrical 1,4-butanediones as major products.

Method of treatment with and compositions containing condensed pyrroles bearing an N-phenyl substituent

Novel N-phenylpyrroles are disclosed that are effective in the treatment of inflammation and pain in mammals and have the formula SPC1 Wherein R is hydrogen, alkyl of one to six carbon atoms, thienyl, phenyl or phenyl substituted by halogen, trifluorometh