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2,4,6-trinitro-N-(5H-tetrazol-5-ylidene)aniline, also known as TNAZ, is a high-energy compound that belongs to the family of tetrazoles. It is characterized by its molecular structure, which includes a central aniline group substituted with three nitro groups at the 2, 4, and 6 positions, and a tetrazol-5-ylidene group attached to the nitrogen atom. 2,4,6-trinitro-N-(5H-tetrazol-5-ylidene)aniline is of interest in the field of explosives and propellants due to its potential high energy density and stability. TNAZ is a derivative of tetrazoles, which are known for their ability to form powerful explosives. The compound's properties, such as its sensitivity to initiation and its thermal stability, are crucial factors in determining its suitability for various applications. Research into compounds like TNAZ is ongoing to explore their potential use in the development of new materials for military and industrial purposes.

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  • 5467-76-5 Structure
  • Basic information

    1. Product Name: 2,4,6-trinitro-N-(5H-tetrazol-5-ylidene)aniline
    2. Synonyms:
    3. CAS NO:5467-76-5
    4. Molecular Formula: C7H4N8O6
    5. Molecular Weight: 294.1408
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 5467-76-5.mol
  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: 468.9°C at 760 mmHg
    3. Flash Point: 237.4°C
    4. Appearance: N/A
    5. Density: 2.29g/cm3
    6. Vapor Pressure: 1.61E-08mmHg at 25°C
    7. Refractive Index: 1.952
    8. Storage Temp.: N/A
    9. Solubility: N/A
    10. CAS DataBase Reference: 2,4,6-trinitro-N-(5H-tetrazol-5-ylidene)aniline(CAS DataBase Reference)
    11. NIST Chemistry Reference: 2,4,6-trinitro-N-(5H-tetrazol-5-ylidene)aniline(5467-76-5)
    12. EPA Substance Registry System: 2,4,6-trinitro-N-(5H-tetrazol-5-ylidene)aniline(5467-76-5)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 5467-76-5(Hazardous Substances Data)

5467-76-5 Usage

Properties

1. Chemical Name: 2,4,6-trinitro-N-(5H-tetrazol-5-ylidene)aniline
2. Common Name: Tetryl
3. Molecular Formula: C7H5N7O6
4. Physical State: Yellow crystalline solid
5. Solubility: Soluble in organic solvents
6. Explosive Nature: Highly explosive
7. Sensitivity: Susceptible to impact, friction, and heat
8. Usage: Primarily used as a military explosive
9. Performance Enhancement: Often used in combination with other high explosives to boost their effectiveness
10. Regulation: Strictly regulated; restricted to licensed professionals in controlled settings
11. Health Effects: Exposure can lead to adverse health effects
12. Handling: Proper handling and disposal procedures are essential

Chemical Structure

Molecular Formula: C7H5N7O6
Structure: 2,4,6-trinitro-N-(5H-tetrazol-5-ylidene)aniline

Physical Characteristics

Appearance: Yellow crystalline solid
Solubility: Soluble in organic solvents

Usage

Military Application: Commonly used as a military explosive
Performance Enhancement: Employed in combination with other high explosives to enhance their performance

Safety Concerns

Explosive Nature: Highly explosive compound
Sensitivity: Sensitive to impact, friction, and heat
Regulation: Strictly regulated substance, restricted to licensed professionals
Health Effects: Exposure can result in adverse health effects, requiring proper handling and disposal measures.

Check Digit Verification of cas no

The CAS Registry Mumber 5467-76-5 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 5,4,6 and 7 respectively; the second part has 2 digits, 7 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 5467-76:
(6*5)+(5*4)+(4*6)+(3*7)+(2*7)+(1*6)=115
115 % 10 = 5
So 5467-76-5 is a valid CAS Registry Number.

5467-76-5Downstream Products

5467-76-5Relevant articles and documents

Thermal characterization and theoretical and experimental comparison of picryl chloride derivatives of heterocyclic energetic compounds

Yigiter, Aynur Ozler,Atakol, Melike Kundurac?,Levent Aksu,Atakol, Orhan

, p. 2199 - 2213 (2017/02/26)

There were 10 nitrogen-rich energetic compounds prepared by the reaction of 2,4,6-trinitrochlorobenzen (picryl chloride) with pyrazole, 1,2,4-triazole, imidazole, 3-aminopyrazole, 3-nitropyrazole, 3-amino-1,2,4-triazole, 3-nitro-1,2,4-triazole, 3,5-diamino-1,2,4-triazole and guanidine. These compounds were characterized with IR spectra, elemental analysis and 1H NMR and 13C NMR methods. They were also examined with thermogravimetry and differential thermal analyses. The heat generated after the explosion was measured by the use of differential scanning calorimetry. The formation enthalpies of some of the products synthesized were determined by the use of Gaussian 09 software, and probable products were estimated from the data reported in the literature. Finally, theoretical explosion energies of these compounds were calculated using the theoretical formation enthalpies and compared with experimental data.

A novel N-N bond cleavage in 1,5-diaminotetrazole: Synthesis and characterization of 5-picrylamino-1,2,3,4-tetrazole (PAT)

Tang, Yongxing,Yang, Hongwei,Ju, Xuehai,Huang, Hui,Lu, Chunxu,Cheng, Guangbin

, p. 4127 - 4131 (2014/03/21)

The reaction of 1,5-diaminotetrazole with picryl chloride (PiCl) forms 5-picrylamino-1,2,3,4-tetrazole (PAT) rather than the expected 1-picrylamino-5-amino-1,2,3,4-tetrazole or 5-picrylamino-1-amino-1,2,3,4- tetrazole. The structure of PAT was confirmed by single-crystal X-ray diffraction. Some of the energetic properties of the synthesized compound were also studied.

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