5469-96-5Relevant academic research and scientific papers
B(C6F5)3-catalyzed tandem protonation/deuteration and reduction of: In situ -formed enamines
Wu, Rongpei,Gao, Ke
, p. 4032 - 4036 (2021/05/19)
A highly efficient B(C6F5)3-catalyzed tandem protonation/deuteration and reduction of in situ-formed enamines in the presence of water and pinacolborane was developed. Regioselective β-deuteration of tertiary amines was achieved with high chemo- and regioselectivity. D2O was used as a readily available and cheap source of deuterium. Mechanistic studies indicated that B(C6F5)3 could activate water to promote the protonation and reduction of enamines. This journal is
REACTION OF N-(2,2-DIPHENYLVINYLIDENE)ANILINES WITH DICHLOROCARBENE
Khlebnikov, A. F.,Novikov, M. S.,Kostikov, R. R.
, p. 1533 - 1537 (2007/10/02)
The reaction of N-(2,2-diphenylvinylidene)anilines with dichlorocarbene, generated by the reaction of chloroform with potassium tert-butoxide, leads to the formation of N-aryl-N-(2,2-diphenylvinyl)carbamoyl chlorides or tert-butyl N-aryl-N-(2,2-diphenylvi
N-NETHYL-N-ANILINOMETHYL DIPHENYLPHOSPHINE OXIDE: A VERSATILE REAGENT FOR THE SYNTHESIS OF ENAMINES
Broekhof, N. L. J. M.,Jonkers, F. L.,Gen, A. van der
, p. 2671 - 2674 (2007/10/02)
Cyclic as well as acyclic ketones, both saturated and α,β-unsatorated, can be converted into their homologous enamines by Horner-Wittig reaction with N-methyl-N-anilinomethyl diphenylphosphine oxide (3).
