54737-47-2Relevant academic research and scientific papers
Phosphazene base-catalyzed hydroamination of aminoalkenes for the construction of isoindoline scaffolds: Application to the total synthesis of aristocularine
Matsuoka, Junpei,Terashita, Maki,Miyawaki, Akari,Tomioka, Kiyoshi,Yamamoto, Yasutomo
supporting information, (2021/12/30)
A method for isoindoline synthesis via phosphazene base-catalyzed intramolecular hydroamination of aminoalkenes was developed. The reaction has a broad functional group tolerance, including for halide, cyano, and methoxy groups, and could also be used to
Manganese-Catalyzed ortho-C?H Alkenylation of Aromatic N?H Imidates with Alkynes: Versatile Access to Mono-Alkenylated Aromatic Nitriles
Yang, Xiaoxu,Jin, Xiqing,Wang, Congyang
, p. 2436 - 2442 (2016/08/16)
So far, the direct C?H alkenylation of aromatic nitriles with alkynes has not been achieved. Herein, we discribe the first manganese-catalyzed C?H alkenylation of aromatic N?H imidates to access mono-alkenylated aromatic nitriles. The reaction is accelerated by the presence of a catalytic amount of sodium pivalate. This protocol is also highlighted by the simple catalytic system, good compatibility of functional groups, and excellent mono-/dialkenylation selectivity as well as E/Z stereoselectivity. (Figure presented.).
Photophysics and photochemistry of intramolecular stilbene-amine exciplexes
Lewis, Frederick D.,Bassani, Dario M.,Burch, Eric L.,Cohen, Bliss E.,Engleman, Jeffrey A.,Reddy, G. Dasharatha,Schneider, Siegfried,Jaeger, Wighard,Gedeck, Peter,Gahr, Michael
, p. 660 - 669 (2007/10/02)
The photophysical and photochemical behavior of a series of trans- (aminoalkyl)stilbenes in which a primary, secondary, or tertiary amine is appended to the stilbene ortho position with a methyl, ethyl, or propyl linker has been investigated. The tertiary
Antiarrhythmic agents. 2, 3, and 4 substituted benzylamines
Remy,van Saun Jr.,Engelhardt
, p. 142 - 148 (2007/10/06)
The synthesis of a series of 2, 3, and 4 substituted benzylamine derivatives is described. These compounds were studied for their effect on experimental cardiac arrhythmias. Many of the derivatives, but in particular 2 (p methoxyphenylethynyl) benzylamine
