32300-73-5Relevant academic research and scientific papers
Phosphazene base-catalyzed hydroamination of aminoalkenes for the construction of isoindoline scaffolds: Application to the total synthesis of aristocularine
Matsuoka, Junpei,Terashita, Maki,Miyawaki, Akari,Tomioka, Kiyoshi,Yamamoto, Yasutomo
supporting information, (2021/12/30)
A method for isoindoline synthesis via phosphazene base-catalyzed intramolecular hydroamination of aminoalkenes was developed. The reaction has a broad functional group tolerance, including for halide, cyano, and methoxy groups, and could also be used to
Reactions of Diene-conjugated 1,3-Dipolar Intermediates: the Formation of Cyclopropaisoquinolines from Benzonitrile o-Alkenylbenzyl Ylides and their Rearrangements to Benzazepines
Motion, Keith R.,Robertson, Ian R.,Sharp, John T.,Walkinshaw, Malcolm D.
, p. 1709 - 1720 (2007/10/02)
The diene-conjugated nitrile ylides 19, generated by 1,3-dehydrochlorination of imidoyl chlorides 18, cyclise at room temperature to give the cyclopropaisoquinolines 21 in a stereospecific reaction.Thermal decomposition of the latter when R1
