54767-28-1 Usage
Properties
1. Chemical Name: 2,7-DIMETHYL-5-SILASPIRO[4.4]NONA-2,7-DIENE
2. Molecular Formula: C9H16Si
3. Physical State: Colorless liquid
4. Structure: Contains a unique spirocyclic structure with a silicon atom
5. Usage: Commonly used in organic synthesis and as a precursor in chemical production
6. Applications: Used in organic chemistry for forming carbon-carbon bonds and creating complex molecular structures
7. Industrial Uses: Building block in pharmaceutical and agrochemical industries
8. Value: Valuable for the development of new drugs and agricultural products
Physical State
Describes its appearance at room temperature.
Structure
Features a spirocyclic arrangement with a silicon atom, contributing to its unique properties.
Usage
Indicates its primary role in chemical synthesis.
Applications
Highlights its importance in organic chemistry for specific tasks like bond formation and complex molecule creation.
Industrial Uses
Discusses its role as a foundational component in pharmaceuticals and agrochemicals.
Value
Emphasizes its significance in advancing drug development and agricultural innovation.
Check Digit Verification of cas no
The CAS Registry Mumber 54767-28-1 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 5,4,7,6 and 7 respectively; the second part has 2 digits, 2 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 54767-28:
(7*5)+(6*4)+(5*7)+(4*6)+(3*7)+(2*2)+(1*8)=151
151 % 10 = 1
So 54767-28-1 is a valid CAS Registry Number.
InChI:InChI=1/C10H16Si/c1-9-3-5-11(7-9)6-4-10(2)8-11/h3-4H,5-8H2,1-2H3
54767-28-1Relevant academic research and scientific papers
Chemistry of Substituted (2-Butene-1,4-diyl)magnesium: A Facile Approach to Complex Carbocycles, Functionalized Ketones and Alcohols, and Silicon-Containing Heterocycles
Rieke, Reuben D.,Xiong, Heping
, p. 3109 - 3118 (2007/10/02)
Highly reactive magnesium reacts with a wide variety of substituted 1,3-dienes to give the corresponding substituted (2-butene-1,4-diyl)magnesium complexes.Reactions of symmetrical (2-butene-1,4-diyl)magnesium with α,ω-alkylene dihalides form three-, four-, five-, and six-membered carbocycles.Significantly, the cyclizations are always stereospecific and completely regioselective.Depending on the initial 1,3-diene and specific electrophiles, uncyclized products can be obtained.Stepwise reactions of (2,3-dimethyl-2-butene-1,4-diyl)magnesium with two different electrophiles afford polyfunctionalized ketones with the generation of a quaternary center.Formal 1,2-additions can be effected in this manner.Substituted five- and six-membered cyclic ketones can also be synthesized in one step by this approach.Treatment of unsymmetrical (2-butene-1,4-diyl)magnesium complexes with triorganosilyl chlorides followed by cyclohexanone results in additions across a terminal double bond with high regioselectivity.Silicon-containing heterocycles or spiro compounds can be readily synthesized by using the bis-Grignard reagents.
