54841-02-0Relevant academic research and scientific papers
Formal Ir-Catalyzed Ligand-Enabled Ortho and Meta Borylation of Aromatic Aldehydes via in Situ-Generated Imines
Bisht, Ranjana,Chattopadhyay, Buddhadeb
supporting information, p. 84 - 87 (2016/01/25)
The ligand-enabled development of ortho and meta C-H borylation of aromatic aldehydes is reported. It was envisaged that while ortho borylation could be achieved using tert-butylamine as the traceless protecting/directing group, meta borylation proceeds via an electrostatic interaction and a secondary interaction between the ligand of the catalyst and the substrate. These ligand-substrate electrostatic interactions and secondary B-N interactions provide an unprecedented controlling factor for meta-selective C-H activation/borylation.
Luminescent organogold(III) complexes with long-lived triplet excited states for light-induced oxidative C-H bond functionalization and hydrogen production
To, Wai-Pong,Tong, Glenna So-Ming,Lu, Wei,Ma, Chensheng,Liu, Jia,Chow, Andy Lok-Fung,Che, Chi-Ming
, p. 2654 - 2657 (2012/04/17)
All that glitters is gold: Highly phosphorescent gold(III) complexes (see picture) with extended π-conjugated cyclometalating ligands exhibit rich photophysical and photochemical properties. They act as efficient photocatalysts/photosensitizers for oxidative functionalizations of secondary and tertiary benzylic amines and homogeneous hydrogen production from a water/acetonitrile mixture. Copyright
