548461-17-2Relevant academic research and scientific papers
Heterolytic dihydrogen activation in an iridium complex with a pendant basic group
Lee, Dong-Heon,Patel, Ben P.,Clot, Eric,Eisenstein, Odile,Crabtree, Robert H.
, p. 297 - 298 (2007/10/03)
Experimental and theoretical studies show that H2 reacts with an Ir phosphine complex having a basic pendant amino group to give either an H2 or an Ir-H...H-N hydrogen-bonded hydride complex, depending on the basicity of the phosphine ligands.
