54848-41-8Relevant academic research and scientific papers
Synthesis of chiral epoxy alcohols: Synthesis of (+)-disparlure
Kang, Suk-Ku,Kim, Yun-Sik,Lim, Jong-Suk,Kim, Kun-Soo,Kim, Sung-Gyu
, p. 363 - 366 (2007/10/02)
(2R,3S)-1,2-Epoxy alcohols 1, (2S,3S)-2,3-epoxy alcohols 2, and (2S,3S)-1,2-epoxy alcohols 3 were prepared from readily available (-)-2-deoxy-D-ribose. Using epoxy alcohol 3b as a chiral synthon, (+)-disparlure, the pheromone of the gypsy moth, Porthetria
(+)-cis-Disparlure: Synthesis and Field Tests
Noe, Christian R.,Knollmueller, Max,Kuerner, Helmut,Steinbauer, Gerhard,Koberg, Helmut,Gaertner, Peter
, p. 101 - 110 (2007/10/02)
A synthesis of (+)-cis-disparlure is described starting from racemic 2-hydroxy-dodecannitrile (2), which is transformed into the O-protected enantiomerically pure cyanohydrine 4.Grignard-reaction followed by reduction with BH3*(CH3)2S yields the correspon
SYNTHESIS OF CHIRAL 1,2-DIOLS AND RELATED COMPOUNDS OF BIOLOGICAL ACTIVITIES VIA STEPWISE RING FISSION OF 5-ALKYL-6,8-DIOXABICYCLOOCTANE SKELETON
Masaki, Yukio,Serizawa, Yuzuru,Nagata, Kinnosuke,Oda, Hirohisa,Nagashima, Hiromu,Kaji, Kenji
, p. 231 - 234 (2007/10/02)
5-Alkyl-7-mesyloxymethyl-6,8-dioxabicyclooctanes, prepared from (+)-tartaric acid, were converted by means of an organoaluminium reagent Et2AlSPh into the pyranoid monothioacetals, which were utilized via the successive thioacetalization
