54848-82-7

Upstream product

• 2117-48-8 triphenyl-vinyl stannane 
• 7669-54-7 2-nitrobenzenesulfenyl chloride 
• 13290-56-7 (2-bromo-ethyl)-(2-nitro-phenyl)-sulfide 
• 72610-20-9 2-chloro-1-(trimethylsilyl)ethyl 2-nitrophenyl sulfide 

Downstream Products

• 72622-66-3 2-nitrophenyl vinyl sulfoxide 
• 57682-92-5 C₁₅H₁₄ClNO₂S₂ 

Relevant academic research and scientific papers

Azo and azoxythiacrown ethers: Synthesis and properties

A series of 16- and 18-membered azo- and azoxythiacrown ethers have been synthesized by reductive macrocyclization of the respective bis(nitrophenoxy) oxaalkanes. The aromatic residues located in the polyether region of the molecule were introduced to mac

Silicon in Synthesis. 8. Vinyltrimethylsilane, a Convenient Ethylene Equivalent for the Synthesis of Vinyl Aryl Sulfides, Vinyl Aryl Sulfoxides, Thiosilylketene Acetals, and Fused Cyclopentenones

Vinyltrimethylsilane reacts with a variety of arylsulfenyl chlorides to give 2-chloro-1-(trimethylsilyl)ethyl aryl sulfide adducts 9-13.These adducts can be converted into vinyl aryl sulfides and vinyl aryl sulfoxides, and for the case of 2-chloro-1-(trimethylsilyl)ethyl phenyl sulfide (11), treatment with 1,5-diazabicyclonon-5-ene (DBN) gave 1-(trimethylsilyl)-1-(phenylthio)ethylene (24). α,β-Unsaturated acid chlorides react with vinyltrimethylsilane in the presence of stannic tetrachloride to give fused cyclopentenones.In all of the reaction described, vinyltrimethylsilane serves as a convenient ethylene equivalent.