72610-20-9

Basic information

• Product Name: 2-chloro-1-(trimethylsilyl)ethyl 2-nitrophenyl sulfide
• Synonyms: 2-chloro-1-(trimethylsilyl)ethyl 2-nitrophenyl sulfide
• CAS NO: 72610-20-9
• Molecular Weight: 289.858
• Mol File: 72610-20-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-chloro-1-(trimethylsilyl)ethyl 2-nitrophenyl sulfide(CAS DataBase Reference)
• NIST Chemistry Reference: 2-chloro-1-(trimethylsilyl)ethyl 2-nitrophenyl sulfide(72610-20-9)
• EPA Substance Registry System: 2-chloro-1-(trimethylsilyl)ethyl 2-nitrophenyl sulfide(72610-20-9)

Safety Data

• Hazardous Substances Data: 72610-20-9(Hazardous Substances Data)

Upstream product

• 7669-54-7 2-nitrobenzenesulfenyl chloride 
• 754-05-2 ethenyltrimethylsilane 

Downstream Products

• 72622-66-3 2-nitrophenyl vinyl sulfoxide 
• 54848-82-7 2-nitrophenyl vinyl sulfide 

Relevant articles and documents

Silicon in Synthesis. 8. Vinyltrimethylsilane, a Convenient Ethylene Equivalent for the Synthesis of Vinyl Aryl Sulfides, Vinyl Aryl Sulfoxides, Thiosilylketene Acetals, and Fused Cyclopentenones

Vinyltrimethylsilane reacts with a variety of arylsulfenyl chlorides to give 2-chloro-1-(trimethylsilyl)ethyl aryl sulfide adducts 9-13.These adducts can be converted into vinyl aryl sulfides and vinyl aryl sulfoxides, and for the case of 2-chloro-1-(trimethylsilyl)ethyl phenyl sulfide (11), treatment with 1,5-diazabicyclonon-5-ene (DBN) gave 1-(trimethylsilyl)-1-(phenylthio)ethylene (24). α,β-Unsaturated acid chlorides react with vinyltrimethylsilane in the presence of stannic tetrachloride to give fused cyclopentenones.In all of the reaction described, vinyltrimethylsilane serves as a convenient ethylene equivalent.