548483-74-5

Upstream product

• 1501995-72-7 (1R,6R,8S)-8-phenethyl-2,9,10-trioxa-1-phosphabicyclo[4.3.1]dec-4-ene-1-oxide 
• 645-49-8 cis-stilben 
• 133271-09-7 C₁₁H₁₄O₂ 
• 106-95-6 allyl bromide 
• 1398307-84-0 (4S,6S)-6-tert-Butyldimethylsilyloxy-8-phenyloct-1-en-4-ol 
• 1398308-08-1 C₁₈H₃₂O₃Si 
• 60340-28-5 (R)-1-phenyl-hex-5-en-3-ol 
• 60340-28-5 (S)-1-phenyl-5-hexen-3-ol 
• 261917-78-6 (S)-3-((tert-butyldimethylsilyl)oxy)-5-phenylpentanal 
• 1379822-84-0 (-)-(S)-1-phenyl-3-(tert-butyldimethylsilyloxy)-hex-5-ene 
• 887195-31-5 (S)-3-acetoxy-1-phenylhex-5-ene 
• 60340-28-5 1-phenylhex-5-en-3-ol 
• 55282-95-6 ethyl (2E)-5-phenylpent-2-enoate 
• 33046-84-3 (2E)-5-phenyl-2-pentenal 

Downstream Products

• 548483-75-6 (4S,6S)-4-Allyl-2,2-dimethyl-6-phenethyl-[1,3]dioxane 
• 485321-73-1 (R)-6-[(E)-3-((4S,6S)-2,2-Dimethyl-6-phenethyl-[1,3]dioxan-4-yl)-propenyl]-5,6-dihydro-pyran-2-one 
• 548483-76-7 (E)-4-((4S,6S)-2,2-Dimethyl-6-phenethyl-[1,3]dioxan-4-yl)-but-2-enal 
• 548483-77-8 (E)-(R)-7-((4S,6S)-2,2-Dimethyl-6-phenethyl-[1,3]dioxan-4-yl)-hepta-1,5-dien-4-ol 
• 548483-78-9 acrylic acid (E)-(R)-1-allyl-4-{(4S,6S)-2,2-dimethyl-6-phenethyl-[1,3]dioxan-4-yl}-but-2-enyl ester 

Relevant academic research and scientific papers

Natural product (+)-Strictifolione synthetic method

The invention discloses a natural product (+)-Strictifolione synthetic method. The method comprises the steps that 3-benzenepropanal and an Evans chiral auxiliary reagent are subjected to an aldol reaction for diisobutyl aluminum hydride reduction and the

An efficient, modular approach for the synthesis of (+)-strictifolione and a related natural product

An efficient, library amenable, "pot economical" total synthesis of (+)-strictifolione and the related natural product, (6R)-6[(E,4R,6R)-4,6- dihydroxy-10-phenyl-1-decenyl]-5,6-dihydro-2H-2-pyrone, are reported. This modular approach takes advantage of tw

A chemoenzymatic asymmetric synthesis of (+)-strictifolione

A chemoenzymatic asymmetric synthesis of the title compound has been developed using an efficient lipase-catalyzed acylation and a chiral reagent-directed diastereoselective allylation as the key steps for incorporating the stereogenic centers. A cross me

Stereoselective total synthesis of (+)-strictifolione and (6R)-6[(E,4R,6R)-4,6-dihydro-10-phenyl-1-decenyl)-5,6-dihydro-2H-2-pyrone

The stereoselective total synthesis of two naturally occurring α-pyrone derivatives, (+)-strictifolione and (6R)-6[(E,4R,6R)-4,6- dihydroxy-10-phenyl-1-decanyl]-5,6-dihydro-2H-2-pyrone has been accomplished involving the Sharpless kinetic resolution and o

Stereoselective total synthesis of (+)-strictifolione and (6R)-6-[(4R,6R)-4,6-dihydroxy-10-phenyldec-1-enyl]-5,6-dihydro-2H-pyran-2-one by Prins reaction and olefin cross-metathesis

Prins and olefin cross-metathesis reactions were used as the key steps for the stereoselective total synthesis of (+)-strictifolione and (6R)-6-[(4R,6R)-4,6-dihydroxy-10-phenyldec-1-enyl]-5,6-dihydro-2H-pyran-2-one. Removal of MOM protecting groups under