548487-75-8

Upstream product

• 623-36-9 (E)-2-methylpent-2-enal 
• 768-33-2 phenyldimethylsilyl chloride 
• 108-24-7 acetic anhydride 

Downstream Products

• 548488-19-3 (-)-acetic acid 2-methyl-3-(dimethylphenylsilyl)-(E)-pent-1-enyl ester 
• 548487-90-7 (2R,3S,4S,5S)-3-acetoxy-4-dimethylphenylsilyl-2,4-dimethyl-5-ethyl-tetrahydrofuran-2-carboxylic acid (S)-4,4-dimethyl-2-oxotetrahydrofuran-3-yl ester 
• 548487-93-0 (2S,3S,4S,5S)-3-benzyloxy-2-benzyloxymethyl-2,4-dimethyl-4-dimethylphenylsilyl-5-ethyltetrahydrofuran 
• 548488-20-6 (2S,3S,4S,5S)-4-dimethylphenylsilyl-3-hydroxy-2-hydroxymethyl-2,4-dimethyl-5-ethyltetrahydrofuran 

Relevant academic research and scientific papers

[3 + 2] annulation of allylic silanes in acyclic stereocontrol: Total synthesis of (9S)-dihydroerythronolide A

The [3 + 2] annulation reactions of allylic silanes can be utilized to achieve acyclic stereocontrol. This method was employed as a key step in an enantioselective total synthesis of (9S)-dihydroerythronolide A. The key annulation reaction served to estab