548488-20-6

Upstream product

• 548487-75-8 acetic acid 2-methyl-3-(dimethylphenylsilyl)-(E)-pent-1-enyl ester 
• 768-33-2 phenyldimethylsilyl chloride 
• 548487-90-7 (2R,3S,4S,5S)-3-acetoxy-4-dimethylphenylsilyl-2,4-dimethyl-5-ethyl-tetrahydrofuran-2-carboxylic acid (S)-4,4-dimethyl-2-oxotetrahydrofuran-3-yl ester 

Downstream Products

• 548487-93-0 (2S,3S,4S,5S)-3-benzyloxy-2-benzyloxymethyl-2,4-dimethyl-4-dimethylphenylsilyl-5-ethyltetrahydrofuran 
• 548488-02-4 (3S,4R,5S,6R,7S,8R,9R)-3,4-dibenzyloxy-9-(p-methoxybenzyloxy)-2,4,6,8,10-pentamethylundec-1-en-5,7-diol 
• 548487-92-9 (2S,3S,4S,5S)-3,4-dibenzyloxy-2,4-dimethyl-5-ethyl-2-triisopropylsiloxymethyltetrahydrofuran 
• 548487-96-3 (2S,3S,4S,5S)-3,4-dibenzyloxy-2,4-dimethyl-5-ethyl-2-iodomethyltetrahydrofuran 
• 548487-91-8 (2S,3S,4S,5S)-3-benzyloxy-2-benzyloxymethyl-2,4-dimethyl-5-ethyl-4-hydroxytetrahydrofuran 
• 548487-95-2 (2S,3S,4S,5S)-3,4-dibenzyloxy-2,4-dimethyl-5-ethyl-2-hydroxymethyltetrahydrofuran 
• 548487-82-7 (4S,5R)-4,5-dibenzyloxy-4,6-dimethylhept-6-en-3-one 
• 548487-97-4 (3R,4S,5R)-3,4-dibenzyloxy-2,4-dimethylhept-1-en-5-ol 

Relevant academic research and scientific papers

[3 + 2] annulation of allylic silanes in acyclic stereocontrol: Total synthesis of (9S)-dihydroerythronolide A

The [3 + 2] annulation reactions of allylic silanes can be utilized to achieve acyclic stereocontrol. This method was employed as a key step in an enantioselective total synthesis of (9S)-dihydroerythronolide A. The key annulation reaction served to estab