54894-35-8Relevant academic research and scientific papers
ALKYLATION DIRECTE DE CETONES ET D'ALDEHYDES EN PRESENCE DE POTASSE SOLIDE EN SUSPENSION
Artaud, I.,Torossian, G.,Viout, P.
, p. 5031 - 5038 (2007/10/02)
Dehydrated solid KOH, suspended in aprotic solvents, is used as a base for ketone and aldehyde alkylation.The best solvent as regards yields and selectivity is DME.The quantity of KOH depends on the carbonyl compound acidity.This method gives as good results as less convenient homogeneous conditions.
Mercury-assisted solvolyses of alkyl halides. Simple procedures for the preparation of nitrate esters, acetate esters, alcohols and ethers
McKillop,Ford
, p. 2467 - 2475 (2007/10/05)
The reactions of a wide variety of alkyl halides with mercury(I) and/or (II) nitrate in 1,2-dimethoxyethane, mercury(II) acetate in acetic acid, aqueous mercury(II) perchlorate, and mercury(II) perchlorate in alcohol solvents have been investigated; as a result, simple high yield procedures for the conversion of alkyl halides into the corresponding nitrate esters, acetate esters, alcohols and ethers have been developed.
