54894-53-0Relevant academic research and scientific papers
Complexes du fer hydro-digermanies: 5-C5H5)(CO)2> (R = Et, Ph) - etude photolytique
Castel, A.,Riviere, P.,Ahbala, M.,Satge, J.,Soufiaoui, M.,Knouzi, N.
, p. 123 - 130 (1993)
The new complexes 5-C5H5)(CO)2> (R=Et or Ph) were prepared by a substitution reaction from the corresponding arylhalohydrodigermanes and the iron salt.Their characterization by IR, 1H and 13C NMR and mass spectroscopy is reported.Photolysis of each complex affords transient monohydrogermylcomplexes 5-C5H5)(CO)2> and dialkylgermylenes which are trapped by 3,5-di-tert-butylorthoquinone and dimethyldisulphide with correct yields.These photolytic reactions are not affected by radical initiators like peroxide.
