54901-66-5Relevant academic research and scientific papers
Stereoselective organocatalytic oxidation of alcohols to enals: A homologation method to prepare polyenes
Chen, Xiaobei,Zhang, Yinan,Wan, Huixin,Wang, Wei,Zhang, Shilei
supporting information, p. 3532 - 3535 (2016/03/04)
A novel method for organocatalytic oxidation through oxidative enamine catalysis was developed with excellent compatibility for the direct syntheses of enals from simple saturated alcohols. By using this amine-catalyzed IBX-oxidation, a wide range of aromatic and aliphatic substituted enals were successfully generated in high yields and exclusively stereoselective E-geometry. Moreover, varying the solvents and/or the loading amounts of IBX allowed for the selective oxidation of alcohols and aldehydes. Importantly, the homologous application of this method provided a selective and efficient way of preparing various highly sensitive conjugated polyene frameworks, which are enriched in natural products.
Larvicidal isoxazoles: Synthesis and their effective susceptibility towards Aedes aegypti larvae
Da Silva-Alves, Diana C.B.,Dos Anjos, Janaina V.,Cavalcante, Nery N.M.,Santos, Geanne K.N.,Navarro, Daniela M.Do A.F.,Srivastava, Rajendra M.
, p. 940 - 947 (2013/03/14)
Twenty 3,5-disubstituted isoxazoles have been synthesized and tested against fourth instar Aedes aegypti larvae. In the synthesis of title compounds, modifications have been made in the C-5 side-chain with a view to test their larvicidal activity. These i
Synthetic applications of 6-hydroxy-1-arylhexane-1,3-diones
De, Dibyendu,Seth, M.,Bhaduri, A. P.
, p. 503 - 506 (2007/10/02)
Facile synthesis of (E)-2-(aroylmethylene)tetrahydrofurans (17-19), 3-aryl-5-(γ-hydroxypropyl)isoxazoles (5-7), 6-hydroxy-1-aryl-3-substitutedaminohex-2-ene-1-ones (14-16), 3-cyano-6-hydroxy-1-arylhex-2-ene-1-ones (23-25) and one pot synthesis of 2-(α-phe
