55048-60-7

Usage

Uses

Used in Pharmaceutical Industry:
[(methoxycarbonyl)disulfanyl]methane is used as a reagent in organic synthesis for the development of new drugs. Its unique properties and versatility make it an essential component in the synthesis of complex molecules with potential pharmaceutical applications.
Used in Agrochemical Industry:
[(methoxycarbonyl)disulfanyl]methane is used as a reagent in the synthesis of agrochemicals, contributing to the development of effective and innovative products for agricultural use.
Used in Research and Development:
[(methoxycarbonyl)disulfanyl]methane is utilized as a precursor in the research and development of new drugs and chemical processes. Its unique structure and properties allow for the exploration of novel chemical reactions and the creation of new compounds with potential applications in various industries.

Upstream product

• 67-56-1 methanol 
• 13063-89-3 ((methyl)dithio)carbonyl chloride 
• 19708-81-7 methyl O-methyldithiocarbonate 

Downstream Products

• 53628-40-3 3-methyl-2-((1S)-1-methylsulfanyl-7-oxo-(1rH,5cH)-4-thia-2,6-diaza-bicyclo[3.2.0]hept-2-en-6-yl)-but-2-enoic acid benzyl ester 
• 69809-90-1 3-methyl-7c-methylsulfanyl-7t-(4-nitro-benzylideneamino)-8-oxo-(6rH)-4-oxa-1-aza-bicyclo[4.2.0]oct-2-ene-2-carboxylic acid benzyl ester 
• 69809-89-8 3-methyl-7c-methylsulfanyl-7t-(4-nitro-benzylideneamino)-8-oxo-(6rH)-4-thia-1-aza-bicyclo[4.2.0]oct-2-ene-2-carboxylic acid 4-nitro-benzyl ester 
• 69809-91-2 3-acetoxymethyl-7c-methylsulfanyl-7t-(4-nitro-benzylideneamino)-8-oxo-(6rH)-4-oxa-1-aza-bicyclo[4.2.0]oct-2-ene-2-carboxylic acid 4-nitro-benzyl ester 
• 40288-89-9 (6R)-3-methyl-7c-methylsulfanyl-7t-(4-nitro-benzylideneamino)-8-oxo-(6rH)-5-thia-1-aza-bicyclo[4.2.0]oct-2-ene-2-carboxylic acid 2,2,2-trichloro-ethyl ester 
• 132261-21-3 C₂₃H₂₀N₂O₃S₂ 
• 132261-22-4 C₂₅H₂₂N₂O₅S₂ 

Relevant academic research and scientific papers

First synthesis of sulfines by direct oxidation of xanthates

Sulfines are formed by the reaction of xanthates with m-chloroperoxybenzoic acid; they are spontaneously converted at ambient temperature to thiocarbonates and dithioperoxycarbonates unless kinetic steric protection provided by a substituent makes the sul

A General Strategy for Elaboration of the Dithiocarbonyl Functionality, -(C=O)SS-: Application to the Synthesis of Bis(chlorocarbonyl)disulfane and Related Derivatives of Thiocarbonic Acids

A variety of sulfenyl chlorides have been reacted with a variety of alkoxythiocarbonyl compounds to give adducts which then lose (spontaneously, or upon thermolysis, or in the presence of Lewis acid catalyst) the alkyl chloride to provide an assortment of dithiocarbonyl compounds in good to excellent yields.The preparations of bis(chlorocarbonyl)disulfane (1), ((trichloromethyl)dithio)carbonyl chloride (2), ((alkoxycarbonyl)dithio)carbonyl chlorides (3 and 4), and (((alkylthio)carbonyl)dithio)carbonyl chlorides (5 and 6) by this methodology were optimized; some of the (alkoxydichloromethyl)disulfanyl adducts, e.g., ROCCl2SS(C=O)Cl (10) and ROCCl2SS(C=O)OR'(54), were reasonable stable and could be isolated.All new compounds were characterized by analytical data, 1H and 13C NMR, IR, UV, and mass spectrometry, and high-yield derivatizations with alcohols or N-methylaniline.The reaction with N-methylaniline was also adapted to a rapid, convenient, and precise analytical-scale assay of mixtures of compounds containing acid chloride and/or sulfenyl chloride functionalities.The kinetics, mechanism, and stereochemistry of the dithiocarbonyl synthesis are discussed.