55075-33-7Relevant academic research and scientific papers
A direct approach for the expedient synthesis of unsymmetrical ethers by employing bromodimethylsulfonium bromide (BDMS) mediated C-S bond cleavage of naphthalene-2-ol sulfides
Islam, Kobirul,Sidick Basha,Dar, Ajaz A.,Das, Deb K.,Khan, Abu T.
, p. 79759 - 79764 (2015)
The unsymmetrical ether derivatives 1-(alkoxy(aryl)methyl)naphthalen-2-ols (3a-q) were synthesized from 1-(aryl(alkyl/arylthio)methyl)-naphthalene-2-ol derivatives (1) and alcohols (2) by cleavage of C-S bond using bromodimethylsulfonium bromide (BDMS) at
Mannich Bases, XXI: Exchange Reactions of Phenolic Mannich Bases
Moehrle, Hans,Miller, Christoph
, p. 229 - 236 (2007/10/02)
Various p-substituted phenolic Mannich bases (and to a minor degree o-substituted derivatives) form alcohols and ethers when heated in aqueous alcohols in the presence of Na2EDTA or acetic acid.The reaction proceeds with amine elimination and subsequent addition of the solvent to the resulting quinone methide.
