55094-26-3Relevant articles and documents
Stereoselective O-Glycosylations by Pyrylium Salt Organocatalysis**
Nielsen, Michael Martin,Holmstr?m, Thomas,Pedersen, Christian Marcus
supporting information, (2021/12/30)
Despite many years of invention, the field of carbohydrate chemistry remains rather inaccessible to non-specialists, which limits the scientific impact and reach of the discoveries made in the field. Aiming to increase the availability of stereoselective
A Mechanistic Probe into 1,2-cis Glycoside Formation Catalyzed by Phenanthroline and Further Expansion of Scope
Li, Jiayi,Nguyen, Hien M.
supporting information, p. 4054 - 4066 (2021/07/16)
Phenanthroline, a rigid and planar compound with two fused pyridine rings, has been used as a powerful ligand for metals and a binding agent for DNA/RNA. We discovered that phenanthroline could be used as a nucleophilic catalyst to efficiently access high
Palladium(ii)-assisted activation of thioglycosides
Escopy, Samira,Singh, Yashapal,Demchenko, Alexei V.
, p. 2044 - 2054 (2021/03/16)
Described herein is the first example of glycosidation of thioglycosides in the presence of palladium(ii) bromide. While the activation with PdBr2alone was proven feasible, higher yields and cleaner reactions were achieved when these glycosylat