5510-99-6

Usage

Chemical Properties

Clear yellow liquid

InChI:InChI=1/C14H22O/c1-5-10(3)12-8-7-9-13(14(12)15)11(4)6-2/h7-11,15H,5-6H2,1-4H3/t10-,11-/m1/s1

Upstream product

• 107-01-7 butene-2 
• 108-95-2 phenol 
• 1849-18-9 2,4-di-(sec-butyl)phenol 
• 13423-74-0 3,5-di-sec.-butyl-4-hydroxybenzoic acid 
• 99-96-7 4-hydroxy-benzoic acid 
• 71-36-3 butan-1-ol 

Downstream Products

• 61283-84-9 (2,6-Di-sec-butyl-phenoxy)-trimethyl-silane 
• 1849-18-9 2,4-di-(sec-butyl)phenol 
• 27144-25-8 C₂₃H₂₉Cl₂NO₃ 
• 27144-22-5 1,3-Di-sec-butyl-5-chloromethyl-2-(4-nitro-phenoxy)-benzene 
• 39252-45-4 Diethyl-dithiocarbamic acid 3,5-di-sec-butyl-4-hydroxy-benzyl ester 
• 39252-46-5 2,2-Bis-(3,5-di-sec-butyl-4-hydroxy-benzyl)-malonic acid dimethyl ester 
• 255386-04-0 ethyl (3,5-di-s-butyl-4-hydroxyphenyl)-2-oxo-acetate 
• 1083093-51-9 (S,S)-2,6-di-sec-butylphenyl benzoate 
• 1083093-45-1 (R,R,R)-(+)-1-phenylethylcarbamic acid 2,6-di-sec-butylphenyl ester 
• 1083093-53-1 2,6-bis((S)-sec-butyl)phenol 
• 1083093-47-3 (R,R)-2,6-di-sec-butylphenol 
• 1083093-43-9 racemic (R)-(+)-1-phenylethylcarbamic acid 2,6-di-sec-butylphenyl ester 
• 89-72-5 2-sec-butylphenol 
• 27192-12-7 2-Acetylamino-2-[3,5-di-sec-butyl-4-(4-nitro-phenoxy)-benzyl]-malonic acid diethyl ester 

Relevant academic research and scientific papers

Cobalt-Nitrenoid Insertion-Mediated Amidative Carbon Rearrangement via Alkyl-Walking on Arenes

We herein disclose the Cp*Co(III)(LX)-catalyzed amidative alkyl migration using 2,6-disubstituted phenyl azidoformates. Upon the cobalt-nitrenoid insertion toward the substituted ortho carbon, an arenium cationic species bearing a quaternary carbon is generated, and a subsequent alkyl migration process is suggested to occur through an unforeseen alkyl-walking mechanism. A quinolinol ligand of the cobalt catalyst system is proposed to facilitate the final product-releasing rearomatization process by serving as an internal base. This new mechanistic mode enabled both [1,2]- and [1,4]-alkyl rearrangements to allow the structural variation of N-heterocyclic compounds.

Substituted aminophosphonate derivatives, process for their preparation and pharmaceutical compositions containing them

The present invention relates to novel aminophosphonate derivatives substituted in α position by phenol groups, of formula (I): STR1 in which: X1, X2, X3, R1, R2, A, B, Z and n are defined in claim 1, as well as their preparations and the pharmaceutical compositions comprising them.

Equilibria for the isomerization of (secondary-alkyl)phenols and cyclohexylphenols

Equilibria of a series of isomerizations and trans-alkylations of alkylphenols have been investigated in the liquid phase over a wide range of temperatures.Equilibria of isomerizations connected with the displacement of a substituent on a benzene nucleus were studied for secondary-butyl, -amyl, -hexyl, and cyclohexyl-phenols, and di-(secondary-butyl)phenols.Equilibria of positional isomerization connected with the displacement of an oxyphenyl radical in an alkyl chain were investigated for oxyphenyl-pentanes, -hexanes, -octanes, and -decanes.Trans-alkylation was investigated for di- and tri-(secondary-butyl)phenols.Values of ΔrH0m and ΔrS0m were found for all investigated reactions.An analysis was made of the thermodynamic quantities for the reactions.Enthalpies of formation of isopropylphenols (IPP) in the gaseous state were calculated.The values of ΔfH0m/(kJ * mol-1) were found at 298.15 K: o-IPP, -(175.3 +/- 2.4); p-IPP, -(175.3 +/- 2.4); m-IPP, -(175.3 +/-2.4); 2,4-di-IPP, -(254.1 +/- 2.8); 2,5-di-IPP, -(254.1 +/- 2.8); 2,6-di-IPP, -(254.1 +/- 2.8); 3,5-di-IPP, -(254.1 +/- 2.8); 2,4,6-tri-IPP, -(333.0 +/- 3.1).