55115-11-2Relevant academic research and scientific papers
1,3-Dipolar Cycloadditions, 88. C-Methyl-N-phenylnitrilimine and the Regiochemistry of its Cycloadditions
Fliege, Werner,Huisgen, Rolf,Clovis, James S.,Knupfer, Hans
, p. 3039 - 3061 (2007/10/02)
The title compound, a representative of the little known C-alkylnitrilimines, is accessible by three routes: NaNO2 elimination from sodium (α-nitroethylidene)phenylhydrazine in boiling acetonitrile, photolysis of 5-methyl-2-phenyltetrazole, and the thermo
ADDITION DE PHENYLHYDRAZONES AUX OLEFINES EN MILIEU NEUTRE
Fevre, G. Le,Hamelin, J.
, p. 887 - 891 (2007/10/02)
Phenylhydrazones may exhibit three types of reactivity towards alkenes: nucleophilic attack by carbon, nucleophilic attack by nitrogen and 1,3-dipolar cycloaddition through the azomethine imine ylide.The course of the reaction depends on the nature of the hydrazone and alkene substituents.
