55136-93-1Relevant articles and documents
Chiral Organometallic Reagents, XVI. Enantiomerization of α-Thio-, α-Seleno-, and α-Telluro-Substituted Alkyllithium Compounds; Kinetic and Mechanistic Studies
Hoffmann, Reinhard W.,Dress, Ruprecht K.,Ruhland, Thomas,Wenzel, Andreas
, p. 861 - 870 (2007/10/02)
The rate of enantiomerization of the racemic α-phenylselenoalkyllithium compound 6 has been determined by dynamic NMR spectroscopy in THF.The enantiomerization rate was found to be first order with respect to monomeric 6 and to show no conspicuous sol