55145-27-2Relevant academic research and scientific papers
ALKYLATIONS ALLYLIQUES CATALYSEES AU NICKEL
Cuvigny, Therese,Julia, Marc
, p. C21 - C24 (1983)
Stable enolates such as diethyl malonate enolate can be smoothly substituted by allylic acetates (or sulfones) in the presence of nickel complexes.Sulfinate ions convert allylic acetates into sulfones.
SUBSTITUTIONS CATALYSEES AU NICKEL D'ACETATES ET DE SULFONES ALLYLIQUES
Cuvigny, Therese,Julia, Marc
, p. 383 - 408 (2007/10/02)
The allylic substitution of stable enolates derived from diethyl malonate, ethyl cyanoacetate, ethyl benzylsulfonylacetate, bis(benzenesulfonyl)methane and sodium p-toluenesulfinate by a variety of allylic esters and sulfones has been investigated.Suitable ligands and reaction conditions have been found to ensure high yields, and in some cases considerable control of the regioselectivity of the reaction.
