55150-33-9Relevant articles and documents
Double molecular recognition with aminoorganoboron complexes: Selective alcoholysis of β-dicarbonyl derivatives
Oishi, Shunsuke,Saito, Susumu
supporting information; experimental part, p. 5395 - 5399 (2012/06/18)
Double duty: Aminoorganoboron (AOB) complexes recognize alcohol and β-dicarbonyl units, and thereby facilitate chemo- and site-selective alcoholysis of the latter (see scheme). The complex activates both reaction partners. This strategy enables C-C, C-N, and C-O bond cleavage in addition/elimination reactions under near neutral pH conditions and provides a new method for functional group conversions. Copyright