5520-88-7Relevant academic research and scientific papers
Synthesis of a New N-Diaminophosphoryl-N'-[(2S)-2-pyrrolidinylmethyl]thiourea as a Chiral Organocatalyst for the Stereoselective Michael Addition of Cyclohexanone to Nitrostyrenes and Chalcones – Application in Cascade Processes for the Synthesis of Polyc
Cruz-Hernández, Carlos,Martínez-Martínez, Eduardo,Hernández-González, Perla E.,Juaristi, Eusebio
supporting information, p. 6890 - 6900 (2018/11/23)
A highly diastereoselective and enantioselective Michael addition of enolizable ketones such as cyclohexanone and acetophenone to a variety of substituted trans-?-nitrostyrenes and chalcones was catalyzed by a novel chiral and unsymmetrical thiourea as or
Three-step synthesis of 2,4-diaryl-5,6,7,8-tetrahydroquinoline derivatives
Gezegen, Hayreddin,Dingil, Alparslan,Ceylan, Mustafa
experimental part, p. 1017 - 1024 (2010/10/21)
(Chemical Equation Presented) Addition of cylohexanone to chalcones, obtained from the appropriate acetophenone and benzaldehyde derivatives, under solvent-free conditions gave 1,5-diketones in good yields. Treatment of 1,5-diketones with ammonium acetate in acetic acid afforded directly 2,4-diaryl-5,6,7,8-tetrahydroquinoline derivatives (7a-u) in high yields. The structures of 7a-u were elucidated by 1H NMR, 13C NMR, IR, and elemental analysis.
