55266-95-0

Basic information

• Product Name: C₁₆H₂₄ClP
• CAS NO: 55266-95-0
• Molecular Weight: 282.793
• Mol File: 55266-95-0.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: C₁₆H₂₄ClP(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₆H₂₄ClP(55266-95-0)
• EPA Substance Registry System: C₁₆H₂₄ClP(55266-95-0)

Safety Data

• Hazardous Substances Data: 55266-95-0(Hazardous Substances Data)

Upstream product

• 55266-95-0 L-menthylphenylchlorophosphine 
• 1610883-70-9 (R_P)-O-(-)-menthyl phenylphosphine oxide 
• 644-97-3 Dichlorophenylphosphine 
• 63474-24-8 (1R,2S,5R)-(-)menthylmagnesium chloride 
• 2216-51-5 (-)-menthol 
• 16052-42-9 (1R,2S,5R)-menthyl chloride 
• 55266-95-0 C₁₆H₂₄ClP 

Downstream Products

• 55266-95-0 C₁₆H₂₄ClP 
• 55266-95-0 C₁₆H₂₄ClP 

Relevant articles and documents

New Access Routes to Privileged and Chiral Ligands for Transition-Metal Catalyzed Hydrogen Autotransfer (Borrowing Hydrogen), Dehydrogenative Condensation, and Alkene Isomerization Reactions

A group of transition-metal catalyzed hydrogen moving reactions, encompassing hydrogen autotransfer (HAT; also called borrowing hydrogen, BH), dehydrogenative condensation (DHC) and alkene isomerization, displays high atom economy and relies on widely ava

Crystallization-Induced Asymmetric Transformation of a Tertiary Phosphine

An equilibrating diastereomer mixture of the tertiary phosphines 5 and 6 (2.5:1 equilibrium ratio) undergoes crystallization-induced asymmetric transformation upon slow evaporation of solvent from refluxing heptane to give a 20:1 ratio in favor of the more stable crystalline isomer 5. The process can also be carried out at room temperature by using iodine to catalyze the interconversion of 5 and 6 via a pentavalent intermediate 8. However, this variation is more sensitive to the purity of the starting phosphine. Crystalline 5 can be converted to the stable borane complex 3, and reductive cleavage of the fluorenyl group using lithium naphthalenide affords the corresponding lithio derivative 10. Alkylation with iodomethane or benzyl bromide affords 13 or 17, respectively, with retention of phosphorus configuration.

Menthyl-substituted Organophosphorus Compounds. Part 6. Preparation of P(L-men)RCl and P(L-men)R(S)Cl (R = Me, Et, iPr, tBu, OR Ph; men = cyclo-C6H9-2-iPr-5-Me) and Nuclear Magnetic Resonance Studies of Configuration and Halogen Exchange

Menthyl-substituted chlorophosphines P(L-men)RCl and thiophosphoryl chlorides P(L-men)R(S)Cl (R = Me, Et, or iPr; men = menthyl, i.e. 2-isopropyl-5-methylcyclohexyl) have been prepared.These series (including compounds with R = Ph and tBu) were subjected