55281-50-0

Upstream product

• 58527-86-9 Benzyl 2,3-di-O-benzyl-α-D-glucopyranoside 
• 142698-31-5 benzyl 2,3-di-O-benzyl-4,6-O-benzylidene-α-D-glucopyranoside 
• 100-51-6 benzyl alcohol 
• 2280-44-6 D-Glucose 
• 79549-73-8 benzyl 4,6-O-(phenylmethylene)-α-D-glucopyranoside 
• 156050-34-9 2-<(2-methylprop-2-enyl)sulfonyl>pyridine 
• 34246-23-6 benzyl D-glucopyranoside 
• 114219-25-9 Toluene-4-sulfonic acid (2R,3R,4S,5R,6S)-4,5,6-tris-benzyloxy-3-hydroxy-tetrahydro-pyran-2-ylmethyl ester 

Downstream Products

• 77977-09-4 benzyl 2,3-di-O-benzyl-6-deoxy-α-D-xylo-hexopyranosid-4-ulose 

Relevant academic research and scientific papers

Synthesis of Bradyrhizose from d -Glucose

We describe the synthesis of the unusual bicyclic sugar bradyrhizose in 14 steps and a 6% overall yield from d-glucose. The synthesis involves the elaboration of a trans-fused carbocyclic ring onto the preexisting glucopyranose framework followed by adjus

Partially Benzylated Derivatives of 6-Deoxy-D-glucose

Several partially benzylated derivatives of 6-deoxy-D-glucose (D-quinovose) were synthesized from appropriate di-O-benzyl-D-glucosides whose primary hydroxyl group is unprotected, via unimolar tosylation and subsequent reduction with LiAlH4.

Branched-chain Sugars. XXII. Synthesis of Benzyl 2,3-Di-O-benzyl- and 2,3-O-Methylene-β-L-threo-pentopyranosid-4-uloses, and the Corresponding 6-Deoxy-α-D-xylo-hexopyranosid-4-uloses

The title compounds were synthesized from L-arabinose and D-glucose as intermediates to a few naturally occurring branched-chain sugars.Oxidation conditions of precursors to the corresponding 4-uloses were examined.