58527-86-9Relevant academic research and scientific papers
Synthesis of Bradyrhizose from d -Glucose
Ngoje, Philemon,Crich, David
supporting information, p. 523 - 527 (2020/01/21)
We describe the synthesis of the unusual bicyclic sugar bradyrhizose in 14 steps and a 6% overall yield from d-glucose. The synthesis involves the elaboration of a trans-fused carbocyclic ring onto the preexisting glucopyranose framework followed by adjus
TANNIN INHIBITORS OF HIV
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Paragraph 0029; 0033, (2013/10/07)
The invention provides a method to prevent or treat HIV-infection with synthetic tannins, and pharmaceutical compositions comprising synthetic tannins.
Regioselective removal of the anomeric O-benzyl from differentially protected carbohydrates
Jalsa, Nigel Kevin
supporting information; scheme or table, p. 6587 - 6590 (2012/02/03)
A mild, regioselective deprotection of the anomeric O-benzyl from multi-functionally protected carbohydrates via catalytic transfer hydrogenation is described. The protocol is tolerant of O-benzyl and O-benzylidene protections at non-anomeric positions, g
Synthesis of monosaccharide-fused azetidines
Michaud, Thierry,Chanet-Ray, Josette,Chou, Sithan,Gelas, Jacques
, p. 253 - 269 (2007/10/03)
Primary amines reacted upon 4,6-ditosylates of glucopyranosides to give an azetidine ring fused on C-4 and C-6 of the pyranose ring. On the other hand, the 4,6-ditosylate of benzyl mannopyranoside led to the 4,6-diamino-4,6-dideoxy derivative in a good yield. All the compounds and their precursors were identified by 1H and 13C NMR spectroscopy. Assignments of proton signals were made unambiguously using homodecoupling experiments.
