55332-53-1Relevant academic research and scientific papers
The Product-forming Step in Palladium-catalysed Methoxycarbonylation of Organic Halides
Milstein, David
, p. 817 - 818 (1986)
Use of trimethylphosphine-palladium complexes renders the product-forming step in palladium-catalysed methoxycarbonylation of benzyl chloride or iodobenzene rate-determining and allows for its direct observation; the product-forming step is alcoholysis of an acylpalladium complex and not reductive elimination of a methoxycarbonylpalladium intermediate.
