Journal of the Chemical Society. Chemical communications p. 817 - 818 (1986)
Update date:2022-08-04
Topics:
Milstein, David
Use of trimethylphosphine-palladium complexes renders the product-forming step in palladium-catalysed methoxycarbonylation of benzyl chloride or iodobenzene rate-determining and allows for its direct observation; the product-forming step is alcoholysis of an acylpalladium complex and not reductive elimination of a methoxycarbonylpalladium intermediate.
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