55343-50-5Relevant articles and documents
Palladium-catalyzed cross-coupling of B-Benzyl-9-borabicyclo[3.3.1]nonane to furnish methylene-linked biaryls
Flaherty, Alice,Trunkfield, Amy,Barton, William
, p. 4975 - 4978 (2007/10/03)
(Chemical Equation Presented) Benzylboranes are noticeably uncommon partners within Suzuki-Miyaura coupling reactions. B-Benzyl-9-BBN was successfully coupled to a range of aryl/heteroaryl bromides, chlorides, and triflates to give pharmacologically important methylene-linked biaryl structures. Activated, deactivated, and sterically hindered substrates were successfully coupled in high yield using Pd(PPh3)4 or Pd(OAc)2 with SPhos as the catalyst system.