5535-51-3Relevant academic research and scientific papers
Metal-free visible-light-promoted C(sp3)-H functionalization of aliphatic cyclic ethers using trace O2
Blackburn, Bryan G.,Cooke, Maria Victoria,Laulhé, Sébastien,Niu, Ben,Sachidanandan, Krishnakumar
supporting information, p. 9454 - 9459 (2021/12/09)
Presented is a light-promoted C-C bond forming reaction yielding sulfone and phosphate derivatives at room temperature in the absence of metals or photoredox catalyst. This transformation proceeds in neat conditions through an auto-oxidation mechanism which is maintained through the leaching of trace amounts of O2 as sole green oxidant. This journal is
Difluoro- and trifluoro diazoalkanes-complementary approaches in batch and flow and their application in cycloaddition reactions
Hock, Katharina J.,Mertens, Lucas,Metze, Friederike K.,Schmittmann, Clemens,Koenigs, Rene M.
, p. 905 - 909 (2017/08/14)
Herein we report on applications of fluorinated diazoalkanes in cycloaddition reactions, with the emphasis on studying subtle differences between diverse fluorinated diazo compounds. These differences led to two major synthetic protocols in batch and flow that allow the safe and scalable synthesis of fluoroalkyl-, sulfone-substituted pyrazolines.
Pyrrolidine derivatives for the treatment of cholecystokinine and gastrine-related disorders
-
, (2008/06/13)
Compounds of formula (I), in which R, R1, R2, R3, R4, R5, R6, and R7 are as defined in the specification. The invention also concerns the salts of said compounds, the preparation thereof and the drugs containing same.
THE APPLICATION OF 2-(4-CHLOROPHENYL)-SULFONYLETHOXYCARBONYL (CPSEC) GROUP IN THE SYNTHESIS OF A DNA SEGMENT USING THE PHOSPHOTRIESTER APPROACH
Josephson, Staffan,Balgobin, Neil,Chattopadhyaya, Jyoti
, p. 4537 - 4540 (2007/10/02)
The new base labile CPSEC group has been successfully employed for the protection of the 5'-hydroxyl function to synthesize a "universal Stop codon" DNA sequence: 5'd(TCAATCAATCA)3'.
