553663-02-8Relevant articles and documents
The 4,6-O-[α-(2-(2-lodophenyl)ethylthiocarbonyl)benzylidene] protecting group: Stereoselective glycosylation, reductive radical fragmentation, and synthesis of β-D-rhamnopyranosides and other deoxy sugars
Crich, David,Yao, Qingjia
, p. 2189 - 2191 (2007/10/03)
(Matrix presented) In the thioglycoside/BSP/Tf2O glycosylation method, the 4,6-O-[α-(2-(2-iodophenyl)ethylthiocarbonyl)benzylidene] group enforces β-selectivity in mannopyranosylations. Following glycosylation, treatment with Bu3SnH