85810-81-7

Basic information

• Product Name: methyl acetyl of methyl phenylglyoxylate
• Synonyms: methyl acetyl of methyl phenylglyoxylate
• CAS NO: 85810-81-7
• Molecular Weight: 210.23
• Mol File: 85810-81-7.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: methyl acetyl of methyl phenylglyoxylate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl acetyl of methyl phenylglyoxylate(85810-81-7)
• EPA Substance Registry System: methyl acetyl of methyl phenylglyoxylate(85810-81-7)

Safety Data

• Hazardous Substances Data: 85810-81-7(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 611-73-4 Benzoylformic acid 
• 15206-55-0 methyl 2-oxo-2-phenylacetate 
• 932-88-7 1-iodo-2-phenylethyne 
• 536-74-3 phenylacetylene 
• 932-87-6 1-Bromo-2-phenylacetylene 
• 124-41-4 sodium methylate 
• 83-13-6 diethyl 2-phenylmalonate 
• 637-44-5 phenylpropyolic acid 
• 67-66-3 chloroform 
• 10028-15-6 ozone 
• 149-73-5 trimethyl orthoformate 

Downstream Products

• 15206-55-0 methyl 2-oxo-2-phenylacetate 
• 111047-52-0 methyl N-p-toluenesulfonyl-1-imino-1-phenylacetate 
• 553663-08-4 (4aR,6R,7R,8S,8aS)-6-Methoxy-7,8-bis-(4-methoxy-benzyloxy)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxine-2-carbothioic acid S-[2-(2-iodo-phenyl)-ethyl] ester 
• 553663-03-9 Acetic acid (2S,4aR,6S,7R,8S,8aR)-7-acetoxy-2-[2-(2-iodo-phenyl)-ethylsulfanylcarbonyl]-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-8-yl ester 
• 553663-07-3 Acetic acid (4aR,6R,7R,8S,8aS)-7-acetoxy-2-[2-(2-iodo-phenyl)-ethylsulfanylcarbonyl]-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-8-yl ester 
• 553663-06-2 (4aR,6R,7R,8R,8aR)-7,8-Dihydroxy-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxine-2-carbothioic acid S-[2-(2-iodo-phenyl)-ethyl] ester 
• 553663-02-8 (4aR,6S,7R,8S,8aR)-6-Methoxy-2-phenyl-7,8-bis-trimethylsilanyloxy-hexahydro-pyrano[3,2-d][1,3]dioxine-2-carboxylic acid methyl ester 
• 51785-62-7 Benzoic acid (2R,3R,4S,5R,6S)-4,5-diacetoxy-6-methoxy-2-methyl-tetrahydro-pyran-3-yl ester 
• 150650-49-0 methyl 2,3-di-O-acetyl-4-O-benzoyl-6-deoxy-β-D-galactopyranoside 
• 733001-99-5 S-ethyl 2-O-benzyl-4,6-O-(α-methoxycarbonyl)benzylidene-3-O-(2-naphthalenylmethyl)-1-thio-α-D-mannopyranoside 
• 553663-05-1 (4aR,6R,7R,8S,8aS)-6-Methoxy-2-phenyl-7,8-bis-trimethylsilanyloxy-hexahydro-pyrano[3,2-d][1,3]dioxine-2-carboxylic acid methyl ester 
• 553663-01-7 (4aR,6S,7R,8R,8aS)-7,8-Dihydroxy-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxine-2-carboxylic acid methyl ester 

Relevant articles and documents

Highly enantioselective aza-henry reaction of ketimines catalyzed by a chiral bifunctional thiourea-tertiary amine derived from quinine

We have developed a highly enantioselective aza-Henry reaction of aryl α-ketoester-derived N-Ts ketimines with a wide range of substrate scope by a simpler bifunctional thiourea-tertiary amine catalyst derived from quinine. A variety of ketimines were investigated and corresponding products were obtained in excellent yields (up to 99% yield) with excellent enatioselectivities (up to 99% ee).

Facile preparation of the methyl acetal of methyl phenylglyoxylate

The methyl acetal of methyl phenylglyoxylate has been prepared from halophenylethynes, N-iodosuccinimide and catalytic amounts of (hydroxy(p-tosyloxy)iodo)benzene or p-toluenesulfonic acid in methanol at room temperature.

Diphenylsilane Reduction of C=O and C=N Bearing Electron-Withdrawing Group in the Presence of Aluminium(III) Chloride

Several α-keto esters and methyl N-p-tolylsulfonyl-2-aryl-2-iminoacetates were reduced to the corresponding α-hydroxy esters and methyl N-p-tolylsulfonyl-2-arylglycinates in high yields by a combination of aluminium(III) chloride and diphenylsilane under operating conditions in which diphenylsilane was added to the pre-formed substrate-aluminium(III) chloride complex in dichloromethane and the mixture stirred.The case of an exactly equivalent amount of aluminium(III) chloride as the substrate resulted in good results.