553664-70-3Relevant articles and documents
Highly enantioselective alk-2-enylation of aldehydes through an allyl-transfer reaction
Nokami, Junzo,Nomiyama, Kenta,Matsuda, Seiji,Imai, Nobuyuki,Kataoka, Kazuhide
, p. 1273 - 1276 (2007/10/03)
Enantiopure homoallylic alcohols such as 1 (conveniently prepared from alk-2-enyl metal reagents with (-)- or (+)-menthone) serve as alk-2-enyl donors to aldehydes. The allyl-transfer reaction, which proceeds via a chairlike six-membered-ring transition s