553665-24-0

Upstream product

• 924288-72-2 (3R,4R)-4-(benzyloxy)-7-((tert-butyldiphenylsilyl)oxy)hept-1-en-3-ol 
• 924288-70-0 4-benzyloxy-4-[5-(1-benzyloxy-4-hydroxy-butyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-butan-1-ol 
• 553665-22-8 2,2-Dimethyl-propionic acid (4R,5S)-5-[(R)-1-hydroxy-4-(2-methoxy-ethoxymethoxy)-butyl]-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl ester 
• 1053694-92-0 (4R,5S)-5-((R)-1-hydroxypent-4-en-1-yl)-N-methoxy-N,2,2-trimethyl-1,3-dioxolane-4-carboxamide 
• 1312103-53-9 (4R,5S)-5-((R)-1-(benzyloxy)pent-4-en-1-yl)-N-methoxy-N,2,2-trimethyl-1,3-dioxolane-4-carboxamide 
• 1312103-56-2 (4R,5S)-5-((R)-1-(benzyloxy)-4-((tert-butyldiphenylsilyl)oxy)butyl)-N-methoxy-N,2,2-trimethyl-1,3-dioxolane-4-carboxamide 
• 1312103-57-3 ((4S,5S)-5-((R)-1-(benzyloxy)-4-((tert-butyldiphenylsilyl)oxy)butyl)-2,2-dimethyl-1,3-dioxolan-4-yl)methanol 
• 1312103-67-5 C₃₃H₄₃IO₄Si 
• 553665-05-7 2,2-Dimethyl-propionic acid (4R,5R)-5-[(R)-1-(tert-butyl-dimethyl-silanyloxy)-4-(2-methoxy-ethoxymethoxy)-butyl]-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl ester 
• 553665-09-1 tert-Butyl-[(R)-1-((4R,5S)-5-iodomethyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-4-(2-methoxy-ethoxymethoxy)-butoxy]-dimethyl-silane 
• 553665-07-9 {(4R,5R)-5-[(R)-1-(tert-Butyl-dimethyl-silanyloxy)-4-(2-methoxy-ethoxymethoxy)-butyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-methanol 
• 848360-44-1 (3aS,4S,6R,6aS)-4-Benzyloxy-6-[(E)-3-(2-methoxy-ethoxymethoxy)-propenyl]-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxole 
• 553665-11-5 (3R,4R)-4-(tert-Butyl-dimethyl-silanyloxy)-7-(2-methoxy-ethoxymethoxy)-hept-1-en-3-ol 
• 553665-03-5 (R)-1-((4S,5R)-5-Hydroxymethyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-4-(2-methoxy-ethoxymethoxy)-butan-1-ol 

Downstream Products

• 553665-17-1 (E)-(5R,6R,10S)-5,6-Bis-benzyloxy-10-[(S)-1-(2-methoxy-ethoxymethoxy)-heptyl]-3,4,5,6,9,10-hexahydro-oxecin-2-one 
• 553665-15-9 (4R,5R)-4,5-Bis-benzyloxy-hept-6-enoic acid (1S,2S)-1-allyl-2-(2-methoxy-ethoxymethoxy)-octyl ester 
• 553664-97-4 (4R,5R)-4,5-bis(benzyloxy)hept-6-enoic acid 
• 852509-25-2 (4R,5R)-4,5-dibenzyloxyhept-6-enoic acid (1'S,1''S)-1'-(1''-benzyloxyheptyl)-3'-butenyl ester 
• 852509-26-3 (5R,6R,7E,10S)-10-[(1'S)-1'-benzyloxyheptyl]-5,6-dibenzyloxy-3,4,5,6,9,10-hexahydro-2H-oxecin-2-one 

Relevant academic research and scientific papers

Enantiodivergent total synthesis of microcarpalide from l-tartaric acid

Stereoselective approach for the synthesis of both enantiomers of bio-active decanolactone microcarpalide is described from l-tartaric acid. The synthesis of the key intermediates en route to the natural product is achieved from l-tartaric acid involving

Stereoselective synthesis of (-)-microcarpalide

A stereoselective approach for the synthesis of the bio-active decanolactone (-)-microcarpalide was achieved from chiral pool tartaric acid. The synthesis of pivotal intermediates en route to the decanolactone was achieved from α-benzyloxy aldehydes deriv

Total synthesis of microcarpalide

A total synthesis of the natural product microcarpalide is described. Ring-closing metathesis of a dienic ester was used as the key step. Mannose was used as the chiral pool material for the construction of the olefinic-acid and a Sharpless asymmetric dih