5537-72-4

Usage

InChI:InChI=1/C13H10O2S/c14-13(15)10-5-4-8-12(9-10)16-11-6-2-1-3-7-11/h1-9H,(H,14,15)

Upstream product

• 585-76-2 m-bromobenzoic acid 
• 1192-40-1 copper(I) thiophenolate 
• 25487-66-5 3-Carboxyphenylboronic acid 
• 108-98-5 thiophenol 
• 591-50-4 iodobenzene 
• 952-97-6 4-nitrophenyl phenyl sulfide 

Downstream Products

• 2548-44-9 3-benzenesulfonyl-benzoic acid 
• 106380-90-9 3-phenylsulfanylbenzamide 
• 114694-98-3 3-phenylsulfanyl-benzoic acid-(4-phenyl-phenacyl ester) 
• 52207-85-9 3-Phenyl-thio-benzoylchlorid 
• 131073-60-4 3-Benzenesulfinyl-benzoic acid 
• 40730-42-5 methyl 3-phenylsulfanylbenzoate 
• 73149-85-6 2-(3-Phenylsulfanyl-benzyl)-malonic acid diethyl ester 
• 73149-88-9 3-(3-Phenylsulfanyl-phenyl)-propionic acid 
• 73149-82-3 Sulfurous acid bis-(3-phenylsulfanyl-benzyl) ester 
• 73149-92-5 5-phenylsulfanyl-indan-1-one 
• 73149-81-2 1-Chloromethyl-3-phenylsulfanyl-benzene 
• 141357-93-9 N,N-dimethyl-3-(phenylthio)benzylamine 

Relevant academic research and scientific papers

SINGLE-STEP SYNTHESIS METHOD OF ARYL THIOL AND APPLICATION THEREOF

The present invention relates to a single-step synthesis method of aryl thiol, and more specifically, to a method of synthesizing aryl thiol in a single-step by making aryl halide react with alkane dithiol in the presence of a transition metal catalyst. According to the present invention, a single-step synthesis method using the transition metal catalyst, the synthesis method which is capable of synthesizing aryl thiol from aryl halide at a high yield, can be provided. Various aryl halides may be applied to the synthesis method. Further, the synthesis method has advantages that an easily usable reagent may be used, operations are simple, and reactions can be performed under mild conditions. In addition, the synthesized aryl thiol may be used in the synthesis of advanced molecules such as diaryl sulfides and benzothiophenes.COPYRIGHT KIPO 2017

Copper(II)-Catalyzed Single-Step Synthesis of Aryl Thiols from Aryl Halides and 1,2-Ethanedithiol

A highly efficient transition metal-catalyzed single-step synthesis of aryl thiols from aryl halides has been developed employing copper(II) catalyst and 1,2-ethanedithiol. The key features are use of readily available reagents, a simple operation, and relatively mild reaction conditions. This new protocol shows a broad substrate scope with excellent functional group compatibility. A variety of aryl thiols are directly prepared from aryl halides in high yields. Furthermore, the aryl thiols are used in situ for the synthesis of more advanced molecules such as diaryl sulfides and benzothiophenes.

Chan-lam-type s-arylation of thiols with boronic acids at room temperature

In this work, an efficient CuSO4-catalyzed S-arylation of thiols with aryl and heteroaryl boronic acids at room temperature is established. This catalytic system can tolerate a wide variety of thiols and arylboronic acids in the presence of only 5 mol % of CuSO4 as the catalyst and inexpensive 1,10-phen?H2O as the ligand. Moreover, this catalytic system used environment-friendly solvent (EtOH) and oxidant (oxygen).

Method for producing Grignard compounds

The invention relates to a process for preparing Grignard compounds of the formula I. The invention additionally relates to compounds of the formula I and to polymer-bound compounds of the formula Ia. The invention further relates to the use of the process for preparing substance libraries and to the use of the compounds of the formulae I and Ia in chemical synthesis.