55373-71-2Relevant academic research and scientific papers
Stereospecific hydrodehalogenation of alkenyl bromides: A new approach to the synthesis of (E)-alkenes
Chelucci, Giorgio
supporting information, p. 4069 - 4072 (2014/04/03)
The pair NaBH4-TMEDA and catalytic PdCl2(PPh 3)2 in THF at room temperature is a mild and efficient system for the hydrodebromination of alkenyl bromides, providing a facile reduction procedure that allows completing the process advantageously, leading from aldehydes to (E)-alkenes. This journal is the Partner Organisations 2014.
One-step synthesis of 1-halo-1,3-butadienes via ruthenium-catalysed hydrohalogenative dimerisation of alkynes
Klein, Hubert,Roisnel, Thierry,Bruneau, Christian,Derien, Sylvie
supporting information, p. 11032 - 11034 (2013/01/15)
An efficient, novel and direct access to 1-halo-1,3-butadienes is developed. This stereoselective ruthenium-catalysed reaction proceeds under mild conditions via the head-to-head oxidative coupling of two alkynes and a concomitant hydrohalogenation.
