55396-46-8

Basic information

• Product Name: (1S,1′R)-(-)-6,7-dimethoxy-1-methyl-2-(1-phenylethyl)-1,2,3,4-tetrahydroisoquinoline
• CAS NO: 55396-46-8
• Molecular Weight: 311.424
• Mol File: 55396-46-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (1S,1′R)-(-)-6,7-dimethoxy-1-methyl-2-(1-phenylethyl)-1,2,3,4-tetrahydroisoquinoline(CAS DataBase Reference)
• NIST Chemistry Reference: (1S,1′R)-(-)-6,7-dimethoxy-1-methyl-2-(1-phenylethyl)-1,2,3,4-tetrahydroisoquinoline(55396-46-8)
• EPA Substance Registry System: (1S,1′R)-(-)-6,7-dimethoxy-1-methyl-2-(1-phenylethyl)-1,2,3,4-tetrahydroisoquinoline(55396-46-8)

Safety Data

• Hazardous Substances Data: 55396-46-8(Hazardous Substances Data)

Upstream product

• 74-83-9 methyl bromide 
• 114105-64-5 (S)-(+)-2-(3,4-dimethoxyphenyl)-N-(1-phenylethyl)acetamide 
• 10313-60-7 3,4-dimethoxyphenylacetyl chloride 
• 55396-39-9 N-[2-(3,4-Dimethoxy-phenyl)-ethyl]-N-((S)-1-phenyl-ethyl)-acetamide 
• 114105-51-0 (S)-(-)-[2-(3,4-dimethoxyphenyl)ethyl](1-phenylethyl)amine 
• 93-40-3 (3,4-Dimethoxyphenyl)acetic acid 
• 114105-55-4 6,7-Dimethoxy-1-methyl-2-((S)-1-phenyl-ethyl)-3,4-dihydro-isoquinolinium; chloride 
• 128592-45-0 N-[2-(3,4-Dimethoxy-phenyl)-ethyl]-N-((S)-1-phenyl-ethyl)-formamide 
• 18006-13-8 methyltriisopropoxytitanium(IV) 

Relevant articles and documents

Synthesis of Tetrahydroisoquinoline Alkaloids and Related Compounds through the Alkylation of Anodically Prepared α-Amino Nitriles

α-Amino nitrile 2a was conveniently prepared in two individual steps from chiral hexafluorophosphate salt isoquinolinium (-)-8b including anodic cyanation as an efficient means to activate the sp3 C1-H bond of the THIQ nucleus. The lithiation o

STEREOSELECTIVE REDUCTIONS OF CHIRAL IMINUM IONS.

Chiral iminium ions derived from α-phenethylamine have been reduced stereoselectively with NaBH4.Diastereoselection of reduction ranged from 88:12 to 94:6.The sense of asymmetric induction has been unambiguously assigned by correlation of reduction produc