55405-89-5

Basic information

• Product Name: N-(1-formylethyl)benzamide
• Synonyms: N-(1-formylethyl)benzamide
• CAS NO: 55405-89-5
• Molecular Weight: 177.203
• Mol File: 55405-89-5.mol

Chemical Properties

• CAS DataBase Reference: N-(1-formylethyl)benzamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-(1-formylethyl)benzamide(55405-89-5)
• EPA Substance Registry System: N-(1-formylethyl)benzamide(55405-89-5)

Safety Data

• Hazardous Substances Data: 55405-89-5(Hazardous Substances Data)

Upstream product

• 7127-19-7 2-phenyl-1,3-oxazoline 
• 201230-82-2 carbon monoxide 
• 51127-13-0 2-phenyl-4-methyl-4H-oxazolin-5-one 
• 24629-34-3 N-(1-hydroxypropan-2-yl)benzamide 

Downstream Products

• 1108739-07-6 (2S)-2-(N-benzoylamino)-1,1-dimethoxypropane 
• 7260-27-7 (R)-N-benzoylalanine methyl ester 
• 7244-67-9 N-benzoyl-L-alanine methyl ester 

Relevant articles and documents

Chemoselective Reduction of Azlactones Using Schwartz's Reagent

Highly chemoselective addition of Schwartz's reagent to widely available azlactones is described. This method allows the preparation of challenged functionalized α-amino aldehydes, in good to high isolated yields at room temperature, after only 2 min reaction. The presence of sensitive functionalities or electronic factors does not compromise the potential of the method. The use of an excess of the reducing reagent gave a very functionalized allylic alcohol derivative in 86% yield.

β-Amidoaldehydes via oxazoline hydroformylation

4-Substituted oxazolines, which are readily synthesized from naturally occurring α-amino acids, are converted efficiently and stereospecifically to β-amidoaldehydes in the presence of synthesis gas and catalytic dicobalt octacarbonyl.

Asymmetric electrochemical oxidation of 1,2-diols, aminoalcohols, and?aminoaldehydes in the presence of chiral copper catalyst

Asymmetric oxidation of 1,2-diols, aminoalcohols, and aminoaldehydes in the presence of copper(II) triflate and (R,R)-Ph-BOX was accomplished by electrochemical method using Br- as a mediator. This oxidation was applicable to kinetic resolution of racemic cis-cycloalkane-1,2-diols, aminoalcohols, and aminoaldehydes to afford optically active compounds with good to high enantioselectivity.

Effecient kinetic resolution of racemic amino aldehydes by oxidation with N-iodosuccinimide

(Chemical Equation Presented) Selective recognition: The first efficient method for the kinetic resolution of racemic amino aldehydes (see scheme, PG=protecting group) is based on a copper(II)/(R,R)-Ph-BOX complex. The coordinated amino aldehydes were tra

A versatile approach to 3-alkyl and 2,3-dialkylpyrroles

A route is described towards N-Benzoyl-3-Alkyl and N-Benzoyl-2,3-Dialkyl pyrroles from α-Amidoketones via an intramolecular Wittig reaction to afford 4-Phenylthio-3-Pyrrolines which are then oxidised to the corresponding sulphones and aromatised by treatm