554416-23-8

Upstream product

• 541-41-3 chloroformic acid ethyl ester 
• 218434-90-3 1-but-3-ynyloxymethyl-4-methoxy-benzene 
• 89238-99-3 O-(4-methoxybenzyl)-trichloroacetimidate 

Downstream Products

• 266675-99-4 tert-Butyl-{(E)-(2S,5R,7R)-5-[2-(4-methoxy-benzyloxy)-ethyl]-7-methoxymethoxy-2,5-dimethyl-deca-3,9-dienyloxy}-diphenyl-silane 
• 266675-84-7 (E)-(4R,6R,9S)-10-(tert-Butyl-diphenyl-silanyloxy)-6-[2-(4-methoxy-benzyloxy)-ethyl]-6,9-dimethyl-deca-1,7-dien-4-ol 
• 266675-81-4 (E)-(3R,6S)-7-(tert-Butyl-diphenyl-silanyloxy)-3-[2-(4-methoxy-benzyloxy)-ethyl]-3,6-dimethyl-hept-4-enoic acid dimethylamide 
• 266675-83-6 (E)-(3S,6S)-7-(tert-Butyl-diphenyl-silanyloxy)-3-[2-(4-methoxy-benzyloxy)-ethyl]-3,6-dimethyl-hept-4-en-1-ol 
• 266675-82-5 (E)-(3R,6S)-7-(tert-Butyl-diphenyl-silanyloxy)-3-[2-(4-methoxy-benzyloxy)-ethyl]-3,6-dimethyl-hept-4-enal 
• 266676-07-7 (2R,3R,Z)-1-((tert-butyldiphenylsilyl)oxy)-7-((4-methoxybenzyl)oxy)-2,5-dimethylhept-4-en-3-ol 
• 266675-80-3 (S)-4-Benzyl-3-[(Z)-(2S,3R)-3-hydroxy-7-(4-methoxy-benzyloxy)-2,5-dimethyl-hept-4-enoyl]-oxazolidin-2-one 
• 266675-85-8 (E)-(2S,5R,7S)-8-(2,2-Dimethyl-[1,3]dioxolan-4-yl)-5-[2-(4-methoxy-benzyloxy)-ethyl]-7-methoxymethoxy-2,5-dimethyl-oct-3-en-1-ol 
• 266676-01-1 (E)-(4S,6R)-6-[2-(4-Methoxy-benzyloxy)-ethyl]-4-methoxymethoxy-6,9-dimethyl-1-nitro-deca-7,9-dien-2-ol 
• 266675-90-5 (1R,3S,4aS,5S,7Z,8aR)-1-[2-(4-methoxybenzyloxy)-ethyl]-3-methoxymethoxy-1,7-dimethyl-5-nitro-1,2,3,4,4a,5,6,8a-octahydronaphthalene 
• 266675-86-9 4-{(E)-(2S,4R)-4-[2-(4-Methoxy-benzyloxy)-ethyl]-2-methoxymethoxy-4,7-dimethyl-octa-5,7-dienyl}-2,2-dimethyl-[1,3]dioxolane 
• 266676-00-0 (E)-(4S,6R)-6-[2-(4-Methoxy-benzyloxy)-ethyl]-4-methoxymethoxy-6,9-dimethyl-deca-7,9-diene-1,2-diol 
• 266675-88-1 1-Methoxy-4-[(E)-(3R,5R)-5-methoxymethoxy-3-methyl-3-((E)-3-methyl-buta-1,3-dienyl)-8-nitro-oct-7-enyloxymethyl]-benzene 
• 266675-87-0 (E)-(3S,5R)-5-[2-(4-Methoxy-benzyloxy)-ethyl]-3-methoxymethoxy-5,8-dimethyl-nona-6,8-dienal 

Relevant academic research and scientific papers

Intramolecular Diels-Alder cyclizations of (E)-1-nitro-1,7,9-decatrienes: Synthesis of the AB ring system of norzoanthamine

Cyclizations of substituted (E)-1-nitro-1,7,9-decatrienes under thermal and Lewis acid conditions have led to the formation of decalin ring systems with excellent endo selectivity. This strategy has been applied to the synthesis of the AB ring system of n

New approach toward the total synthesis of (+)-aphidicolin by tandem transannular Diels-Alder/aldol strategy

The synthesis of a 15-membered macrocyclic triene containing all the required substituents of ring A of (+)-aphidicolin (1) is reported. This compound underwent a thermal transannular cycloaddition followed by an intramolecular aldol reaction to yield tet