554447-15-3Relevant articles and documents
Indium-mediated catalytic enantioselective allylation of N -benzoylhydrazones using a protonated chiral amine
Kim, Sung Jun,Jang, Doo Ok
supporting information; experimental part, p. 12168 - 12169 (2010/10/03)
A catalytic enantioselective indium-mediated allylation of N-benzoylhydrazones in conjunction with a protonated chiral amine affording enantioenriched homoallylic amines with an extremely high level of enantioselectivity and chemical yield was developed.
The sulfinyl moiety in Lewis base-promoted allylations
Fulton, J. Robin,Kamara, Lamin M.,Morton, Simon C.,Rowlands, Gareth J.
experimental part, p. 9134 - 9141 (2010/01/06)
By employing Senanayake's oxathiazolidine-2-oxide reagent, a collection of sulfinamides was prepared and provided the first examples of sulfinamides promoting the allylation of benzaldehyde and N-benzoylhydrazones with allyltrichlorosilane. The optimum su
Indium-mediated asymmetric allylation of acylhydrazones using a chiral urea catalyst
Tan, Kian L.,Jacobsen, Eric N.
, p. 1315 - 1317 (2008/04/05)
(Chemical Equation Presented) Urea-ka! A new role for urea-based chiral catalysts has been uncovered in the asymmetric allylation of acylhydrazones with allylindium reagents (see scheme; Bz: benzoyl). The best results were obtained using the bifunctional